UPSI Digital Repository (UDRep)
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Abstract : |
The application of multiwalled carbon nanotubes (MWCNTs) paste electrode modified with chloropalladium(II) complex in the analysis of trace nickel is presented in this work. The chloropalladium(II) complex was characterized by fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (NMR), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), X-ray photoelectronspectroscopy (XPS), scanning electronmicroscope (SEM), and transmissionelectronmicroscope (TEM). Several operational parameters influencing the electroanalytical response of the modified electrode were optimized, such as the different composition of modifier, pH ofthe solution, accumulation potential, and accumulation time. At optimal condition a linear plot for nickel concentration between 10 nM to 1.0 M with a limit of detection 7.4 nM were obtained. The relative standard deviation for the 1.0 M of Ni(II) was 4.0% (n = 5). This study shows that with the exception of Co2+, excess concentration (in 10 and 100-fold concentration) of other metal ions such as Zn2+, Cu2+, Cd2+, Mg2+, Ca2+, Ce3+, and Ba2+ did not influence the nickel response. The viability of the proposed electrodes for the determination of nickel in vegetables and different water samples was evaluated. Results were compared with those from inductively coupled plasma-optical emission spectrometry (ICP-OES). |
References |
[1] M. Anke, L. Angelow, M. Glei, M. Müller, H. Illing, The biological importance of nickel in the food chain, Fresenius J. Anal. Chem. 352 (1995) 92–96. [2] E. Denkhaus, K. Salnikow, Nickel essentiality toxicity, and carcinogenicity, Crit. Rev. Oncol. Hematol. 42 (2002) 35–56. [3] K. Salnikow, X. Li, M. Lippmann, Effect of nickel and iron co-exposure on human lung cells, Toxicol. Appl. Pharmacol. 196 (2004) 258–265. [4] P. Olmedo, A. Pla, A.F. Hernández, O. López-Guarnido, L. Rodrigo, F. Gil, Validation of a method to quantify chromium cadmium, manganese, nickel and lead in human whole blood, urine, saliva and hair samples by electrothermal atomic absorption spectrometry, Anal. Chim. Acta 659 (2010) 60–67. [5] P. Vinas, ˜ M. Pardo-Martínez, M. Hernández-Córdoba, Determination of copper cobalt, nickel, and manganese in baby food slurries using electrothermal atomic absorption spectrometry, J. Agr. Food Chem. 48 (2000) 5789–5794. [6] L. Zhao, S. Zhong, K. Fang, Z. Qian, J. Chen, Determination of cadmium(II) cobalt(II), nickel(II), lead(II), zinc(II), and copper(II) in water samples using dual-cloud point extraction and inductively coupled plasma emission spectrometry, J. Hazard. Mater. 239 (2012) 206–212. [7] A. Beiraghi, S. Babaee, M. Roshdi, Simultaneous preconcentration of cadmium, cobalt and nickel in water samples by cationic micellar precipitation and their determination by inductively coupled plasma-optical emission spectrometry, Microchem. J. 100 (2012) 66–71. [8] R. Galbeiro, S. Garcia, I. Gaubeur, A green and efficient procedure for the preconcentration and determination of cadmium nickel and zinc from freshwater, hemodialysis solutions and tuna fish samples by cloud point extraction and flame atomic absorption spectrometry, J. Trace Elem. Med.Biol. 28 (2014) 160–165. [9] C¸ .A. S¸ ahin, M. Efec¸ ınar, N. S¸ atıroglu, ˘ Combination of cloud point extraction and flame atomic absorption spectrometry for preconcentration and determination of nickel and manganese ions in water and food samples, J. Hazard. Mater. 176 (2010) 672–677. [10] Y. Wang, K. Du, Y. Chen, Y. Li, X. He, Electrochemical determination of lead based on metal–organic framework MIL-101 (Cr) by differential pulse anodic stripping voltammetry, Anal. Methods 8 (2016) 3263–3269. [11] Z. Li, S. Xia, J. Wang, C. Bian, J. Tong, Determination of trace mercury in water based on N-octylpyridinium ionic liquids preconcentration and stripping voltammetry, J. Hazard. Mater. 301 (2016) 206–213. [12] G. Zhao, Y. Si, H. Wang, G. Liu, A portable electrochemical detection system based on graphene/ionic liquid modified screen-printed electrode for the detection of cadmium in soil by square wave anodic stripping voltammetry, Int. J. Electrochem. Sci. 11 (2016) 54–64. [13] C. Zhang, Y. Zhou, L. Tang, G. Zeng, J. Zhang, B. Peng, X. Xie, C. Lai, B. Long, J.Zhu, Determination of Cd2+ and Pb2+ based on mesoporous carbon nitride/self-doped polyaniline nanofibers and square wave anodic stripping voltammetry, Nanomaterials 6 (2016) 7–18. [14] S.F. Zhou, X.J. Han, H.L. Fan, Q.X. Zhang, Y.Q. Liu, Electrochemical detection of As(III) through mesoporous MnFe 2 O 4 nanocrystal clusters by square wave stripping voltammetry, Electrochim. Acta 174 (2015) 1160–1166. [15] B. Bas,´ K. Wegiel, ˛ K. Jedlinska, ´ The renewable bismuth bulk annular band working electrode: fabrication and application in the adsorptive stripping voltammetric determination of nickel(II) and cobalt(II), Anal. Chim. Acta 881 (2015) 44–53. [16] A. Ferancová, M.K. Hattuniemi, A.M. Sesay, J.P. Räty, V.T. Virtanen, Electrochemical monitoring of nickel(II) in mine water, Mine Water Environ. (2015) 1–6. [17] A. Ferancová, M.K. Hattuniemi, A.M. Sesay, J.P. Räty, V.T. Virtanen, Rapid and direct electrochemical determination of Ni(II) in industrial discharge water, J. Hazard. Mater. 306 (2016) 50–57. [18] A. Mardegan, S. Dal Borgo, P. Scopece, L.M. Moretto, S.B. Hocevar, ˇ P. Ugo, Simultaneous adsorptive cathodic stripping voltammetric determination of nickel(II) and cobalt(II) at an in situ bismuth-modified gold electrode, Electroanalysis 25 (2013) 2471–2479. [19] G. Alves, J.M. Magalhães, H.M. Soares, Simultaneous determination of nickel and cobalt using a solid bismuth vibrating electrode by adsorptive cathodic stripping voltammetry, Electroanalysis 25 (2013) 1247–1255. [20] A. Bobrowski, A. Królicka, M. Maczuga, J. Zarebski, ˛A novel screen-printedelectrode modified with lead film for adsorptive stripping voltammetric determination of cobalt and nickel, Sens. Actuators B: Chem. 191 (2014) 291–297. [21] K. Tyszczuk-Rotko, R. Metelka, K. Vytras, ˇ M. Barczak, Lead film electrode prepared with the use of a reversibly deposited mediator metal in adsorptive stripping voltammetry of nickel, Electroanalysis 26 (2014) 2049–2056. [22] S. Neodo, M. Nie, J.A. Wharton, K.R. Stokes, Nickel-ion detection on a boron-doped diamond electrode in acidic media, Electrochim. Acta 88 (2013) 718–724. [23] W. Tang, J. Bin, W. Fan, Z. Zhang, Y. Yun, Y. Liang, Simultaneous determination of lead and tin at the bismuth film electrode by square wave stripping voltammetry and chemometric methods, Anal. Methods 8 (2016) 5475–5486. [24] W.J. Yi, Y. Li, G. Ran, H.Q. Luo, N.B. Li, Determination of cadmium(II) by square wave anodic stripping voltammetry using bismuth–antimony film electrode, Sens. Actuators B: Chem. 166 (2012) 544–548. [25] J.H. Luo, X.X. Jiao, N.B. Li, H.Q. Luo, Sensitive determination of Cd (II) by square wave anodic stripping voltammetry with in situ bismuth-modified multiwalled carbon nanotubes doped carbon paste electrodes, J. Electroanal.Chem. 689 (2013) 130–134. [26] Z. Li, L. Chen, F. He, L. Bu, X. Qin, Q. Xie, S. Yao, X. Tu, X. Luo, S. Luo, Square wave anodic stripping voltammetric determination of Cd2+ and Pb2+ at bismuth-film electrode modified with electroreduced graphene oxide-supported thiolated thionine, Talanta 122 (2014) 285–292. [27] G.H. Hwang, W.K. Han, J.S. Park, S.G. Kang, Determination of trace metals by anodic stripping voltammetry using a bismuth-modified carbon nanotube electrode, Talanta 76 (2008) 301–308. [28] O.A. Farghaly, M.A. Ghandour, Square-wave stripping voltammetry for direct determination of eight heavy metals in soil and indoor-airborne particulate matter, Environ. Res. 97 (2005) 229–235. [29] T.M. Arantes, A. Sardinha, M.R. Baldan, F.H. Cristovan, N.G. Ferreira, Lead detection using micro/nanocrystalline boron-doped diamond by square-wave anodic stripping voltammetry, Talanta 128 (2014) 132–140. [30] M.I. Saidin, I.M. Isa, M. Ahmad, N. Hashim, A. Kamari, S. Ab Ghani, M.S. Suyanta, Square wave anodic stripping voltammetry of copper(II) at a MWCNT paste electrode modified with a tetracarbonylmolybdenum(0) nanocomposite, Microchim. Acta 183 (2016) 1441–1448. [31] I.M. Isa, M.I. Saidin, M. Ahmad, N. Hashim, S. Ab Ghani, M.S. Suyanta, Development of new copper(II) ion-selective poly (vinyl chloride) membrane electrode based on 2,6-diacetylpyridine-(1R)-(−)-fenchone diazine ligand, Int J. Electrochem. Sci. 8 (2013) 11175–11185. [32] A.L. Patterson, The Scherrer formula for X-ray particle size determination, Phys. Rev. 56 (1939) 978. [33] G. Lai, Y. Liu, A. Yu, D. Han, H. Zhang, Simultaneous sensitive determination of dopamine and uric acid in the presence of excess ascorbic acid with a magnetic chitosan microsphere/thionine modified electrode, Anal. Lett. 46 (2013) 1525–1536. [34] R.M. Tehrani, H. Ghadimi, S. Ab Ghani, Electrochemical studies of two diphenols isomers at graphene nanosheet-poly (4-vinyl pyridine) composite modified electrode, Sens. Actuators B: Chem. 177 (2013) 612–619. [35] X.C. Fu, J. Wu, J. Li, C.G. Xie, Y.S. Liu, Y. Zhong, J.H. Liu, Electrochemical determination of trace copper(II) with enhanced sensitivity and selectivity by gold nanoparticle/single-wall carbon nanotube hybrids containing three-dimensional l-cysteine molecular adapters, Sens. Actuators B: Chem.182 (2013) 382–389. [36] Y. Dong, Y. Zhou, Y. Ding, X. Chu, C. Wang, Sensitive detection of Pb(II) at gold nanoparticle/polyaniline/graphene modified electrode using differential pulse anodic stripping voltammetry, Anal. Methods 6 (2014) 9367–9374. [37] M. Ghiaci, B. Rezaei, M. Arshadi, Characterization of modified carbon paste electrode by using Salen Schiff base ligand immobilized on SiO 2–Al 2 O 3 as a highly sensitive sensor for anodic stripping voltammetric determination of copper (II), Sens. Actuators B: Chem. 139 (2009) 494–500. [38] J.G. Osteryoung, R.A. Osteryoung, Square wave voltammetry, Anal. Chem. 57 (1985) 101A–110A. [39] Q. Zhao, Y. Chai, R. Yuan, J. Luo, Square wave anodic stripping voltammetry determination of lead based on the Hg(II) immobilized graphene oxide composite film as an enhanced sensing platform, Sens. Actuators B: Chem. 178 (2013) 379–384. [40] J. Wang, Ü.A. Kirgöz, J. Lu, Stripping voltammetry with the electrode material acting as abuilt-in’internal standard, Electrochem. Commun. 3 (2001) 703–706. [41] O. Estévez-Hernández, I. Naranjo-Rodríguez, J.H.H. de Cisneros, E. Reguera, Evaluation of carbon paste electrodes modified with 1-furoylthioureas for the analysis of cadmium by differential pulse anodic stripping voltammetry, Sens. Actuators B: Chem. 123 (2007) 488–494. [42] L. Zhu, L. Xu, B. Huang, N. Jia, L. Tan, S. Yao, Simultaneous determination of Cd(II) and Pb(II) using square wave anodic stripping voltammetry at a gold nanoparticle-graphene-cysteine composite modified bismuth film electrode, Electrochim. Acta 115 (2014) 471–477. [43] F. Fathirad, D. Afzali, A. Mostafavi, T. Shamspur, S. Fozooni, Fabrication of a new carbon paste electrode modified with multi-walled carbon nanotube for stripping voltammetric determination of bismuth (III), Electrochim. Acta 103 (2013) 206–210. [44] A. Afkhami, H. Ghaedi, T. Madrakian, M. Rezaeivala, Highly sensitive simultaneous electrochemical determination of trace amounts of Pb (II) and Cd (II) using a carbon paste electrode modified with multi-walled carbon nanotubes and a newly synthesized Schiff base, Electrochim. Acta 89 (2013) 377–386. |
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