Synthesis and application of 2-(5-bromo- 2hydroxybenzylidene) toluenesulfonohydrazide as a shift base ionophore for highly selective copper(II) membrane electrode

Illyas Md Isa

QR Code Link :
Type :	article
Subject :	Q Science (General)
Main Author :	Illyas Md Isa
Additional Authors :	Nazihah Mohd Noor Yusnita Juahir Norhayati Hashim Hapipah Mohd Ali
Title :	Synthesis and application of 2-(5-bromo- 2hydroxybenzylidene) toluenesulfonohydrazide as a shift base ionophore for highly selective copper(II) membrane electrode

Year of Publication :

2017

Abstract :

The construction of a potentiometric copper(II) ion electrode based on 2’-(5-bromo-2-hydroxybenzylidene) toluenesulfonohydrazide (5BrSALMeBSH) as an ionophore has been developed.The designed electrode having a different composition of poly(vinyl chloride) (PVC), plasticizers and ionophore showed that sensor with membrane composition 5BrSALMeBSH: PVC: DOP in the ratio of 7:40:56 (w/w) gave the best response. It exhibited a wide linear response with a Nernstian slope of 29.34 mV per decade over the concentration range of 1.0 x 10-5 – 1.0 x 10-1 M Cu(II) ions. Under the optimized conditions, the electrode has a detection limit of 3.98 x 10-6 M and the working pH range of 3.0 - 6.0 with response time less than the 20s. The proposed electrode is stable for about two months and exhibits good selectivity for Cu(II) ions over Zn2+, Co2+ , Ni2+, Pb2+ ,Mg2+,Ba2+,Ca2+,Cd 2+,Ce3+,K+,Na+.Designation of this easy and inexpensive electrode was used to determine a copper ion in wastewater samples, and the results obtained shown a sync relation with spectroscopy method which is AAS method conducted.

References

1. M. N. Kopylovich, K. T. Mahmudov, and A. J. L. Pombeiro, J. Hazard. Mater, 186 (2011) 1154. 2. J. Bai, Y. Chen, P. Li, D. Sun, and Y. Tang, JEAC, 754 (2015) 1. 3. I. Vopálenská, L. Váchová, and Z. Palková, Biosens. Bioelectron., 72 (2015) 160. 4. I. Isa, M. I. Saidin, M. Ahmad, S. Mustaffa, and S. A. Ghani, Int. J. Electrochem. Sci, 7 (2012) 9536. 5. A.S.M. Pujol, M.Cuillel, O.Renaudet, C.Lebrun, P.Charbonnier, D.Cassio, C. Gateau, P.Dulmy, J.Am.Chem.Soc., 133 (2010) 286. 6. E. Gaggeli, H.Kozlowski, D.Valensin, G.Valensin, Chem Rev., 106 (2006) 1995. 7. G.J Brewer, Chem.Res. Toxicol., 23 (2009) 319. 8. M. Ghanei-Motlagh, M. A. Taher, V. Saheb, M. Fayazi, and I. Sheikhshoaie, Electrochim. Acta, 56 (2011) 5376. 9. R. K. Mahajan and P. Sood, Int. J. Electrochem. Sci., 2 (2007) 832. 10. V. K. Gupta, a. K. Jain, G. Maheshwari, H. Lang, and Z. Ishtaiwi, Sens. Actuators, B, 117 (2006) 99. 11. V. K. Gupta, L. P. Singh, R. Singh, N. Upadhyay, S. P. Kaur, and B. Sethi, J. Mol. Liq., 174 (2012)11. 12. I. Isa, M. I. Saidin, M. Ahmad, N. Hashim, and S. A. Ghani, Int. J. Electrochem. Sci, 8 (2013) 11175. 13. G. Dimeski, T. Badrick, A. S. John, Clin Chim Acta., 411 (2010)309. 14. V. K. Gupta, R. N. Royal, M. Al Khayat, P. Kumar, N. Bacheti, Talanta., 69 (2006) 1149. 15. M. A. Álvarez, G. Carrillo, Talanta, 97 (2012) 505. 16. B. Feist, B. Mikula, K. Pytlakowska, B. Puzio, F. Buhl, J. Hazard. Mater., 152 (2008) 1122. 17. E. L. da Silva, E. M. Ganzarolli, E. Carasek, Talanta, 62 (2004) 727. 18. S. K. Alpat, S. Alpat, B. Kutlu, O. Ozbayrak, and H. B. Buyukisik, Sens. Actuators, B, 128 (2008) 273. 19. I. Lavilla, M. Costas, S. Gil, S. Corderí, G. Sánchez, C.Bendicho, Talanta, 93 (2012) 111. 20. S. Chandra, D. Singh, and A. Sarkar, Chinese J. Chem. Eng. 22 (2014) 480. 21. E. Lindner and B. D. Pendley, Anal. Chim. Acta, 762 (2013) 1. 22. L. P. Singh and J. M. Bhatnagar, Talanta, 64 (2004) 313. 23. I.M. Isa, S. Ab Ghani , Talanta, 71 (2007) 452. 24. I. M. Isa, S. Mustafar, M. Ahmad, N. Hashim, S.A Ghani, Talanta, 87(2011)230. 25. N. Bakeman, I. M. Isa, N.M Ali, M.Ahmad, S.A Ghani, Int.J. Electrochem. Sci, 7(2012) 4574. 26. H. M. Ali, J. Yusnita, M. R. Rizal, and S. W. Ng, Acta Crystallogr. Sect. E Struct. Reports Online, 63 (2007) 2937. 27. T. Rostazin, E. Bakker, K. Suzuki, and W.Simon, Anal. Chim. Acta, 280 (1993) 197. 28. H.A. Zamani, Chinese Chem. Lett., 22 (2011) 701. 29. V. K. Gupta, A. K. Jain, S. Agarwal, and G. Maheshwari, Talanta 71 (2007) 1964. 30. E. Ammann, E. Pretsch, W. Simon, E. Lindner, A. Bezegh, And E. Pungor, Anal. Chim. Acta, 171 (1985) 119. 31. M. de los A, A. Perez, L.P. Martin, J.C. Quintana, M. Yazdani-Pedram, Sens. Actuators B 89 (2003) 262. 32. W. Zhang, L. Jenny, U.E. Spichiger, Anal. Sci. 16 (2000) 11. 33. M. Telting-Diaz, E. Bakker, Anal. Chem. 73 (2001) 5582. 34. R.P. Buck, V.V. Cosofort, E. Linder, Anal. Chim. Acta, 282 (1993) 273. 35. F.J. Sa’ez de Viteri, D. Diamond, Analyst 119 (1994) 749.

This material may be protected under Copyright Act which governs the making of photocopies or reproductions of copyrighted materials.
You may use the digitized material for private study, scholarship, or research.

Back to previous page