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Type :thesis
Subject :QD Chemistry
Main Author :Nur Hidayah Adenan
Title :Pengekstrakan dan pencirian hidroksiapatit daripada tulang lembu dan sisik ikan menggunakan kaedah rawatan alkali
Place of Production :Tanjong Malim
Publisher :Fakulti Sains dan Matematik
Year of Publication :2018
Corporate Name :Universiti Pendidikan Sultan Idris
PDF Guest :Click to view PDF file

Abstract : Universiti Pendidikan Sultan Idris
Kajian ini bertujuan untuk mengekstrak dan mencirikan hidroksiaptit (HA) daripada tulang lembu dan sisik ikan menggunakan kaedah rawatan alkali pada kepekatan yang berbeza. Spektroskopi inframerah (FTIR) dan analisis pembelauan sinar-X (XRD) telah digunakan untuk mencirikan bahan HA daripada tulang lembu (HATL) dan sisik ikan (HASI). Analisis FTIR terhadap sampel HATL dan HASI membuktikan kewujudan kumpulan berfungsi fosfat dan hidroksil di dalam kedua-dua sample. Keputusan XRD menunjukkan difragtogram HA tulang lembu dan HA sisik ikan sepadan dengan difragtogram HA piawai. Keputusan XRD mengesahkan kehadiran fasa kedua iaitu beta trikalsium fosfat (β-TCP) daripada HASI selepas disinter pada suhu 1200 °C. Analisis termogravimetri (TGA) menunjukkan tulang lembu dan sisik ikan yang dirawat dengan 5M NaOH berjaya menyingkirkan bahan organik yang paling tinggi. Mikroskop imbasan elektron (SEM) telah digunakan untuk mengkaji morfologi apatit yang diperolehi. Analisis SEM menunjukkan size zarah HATL selepas rawatan alkali adalah sekitar 53 nm manakala untuk HASI adalah sekitar 36 nm. Analisis tenaga serakan sinar X (EDX) menunjukkan nisbah Ca/P adalah 1.75 dan 1.83 untuk tulang lembu dan sisik ikan masing-masing. Ujian kelarutan menunjukkan kelarutan bahan HASI adalah lebih tinggi berbanding dengan HATL. Kedua-dua bahan HA daripada tulang lembu dan sisik ikan adalah berpotensi digunakan sebagai sumber kalsium untuk makanan tambahan

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