AbstractMallee Biomass is considered to be a second-generation renewable feedstock in Australia and will play an important role in bioenergy development in Australia. Its production is of large-scale, low cost, small carbon footprint and high energy efficiency. However, biomass as a direct fuel is widely dispersed, bulky, fibrous and of high moisture content and low energy density. High logistic cost, poor grindability and mismatch of fuel property with coal are some of the key issues that impede biomass utilisation for power generation. Therefore, innovations are in urgent need to improve biomass volumetric energy densification, grindability and good fuel matching if co-fired with coal. Biomass pyrolysis is a flexible and low-cost approach that can be deployed for this purpose. Via pyrolysis, the bulky biomass can be converted to biomass-derived high-energy-density fuels such as biochar and/or biooil. So far there has been a lack of fundamental understanding of mallee biomass pyrolysis and pr.....