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Ferrihydrite-chitosan nanocomposite as a recyclable flocculant for palm oil mill effluent

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General Information
Title
Ferrihydrite-chitosan nanocomposite as a recyclable flocculant for palm oil mill effluent
Type
Article
Main Author
Juliana Jumadi
Additional Authors
  • Azlan Kamari
  • Nurulsaidah Abdul Rahim
  • Norjan Yusof
Subject
H Social Sciences
ISSN
0127-9696
Language Code
eng
Bibliographic Details
Place of Production
Tanjung Malim
Publisher
Fakulti Sains dan Matematik
Year of publication
2024
Notes
Jurnal Teknologi
Degree Type
Others
Corporate Name
Universiti Pendidikan Sultan Idris
HTTP Link
Access Web Resource

Abstract

In the present study, ferrihydrite-chitosan nanocomposite (FCN) was successfully produced by co-precipitation method and used for the first time as a recyclable flocculant for pre-treatment of palm oil mill effluent (POME). The physicochemical properties of FCN were studied using Raman spectrometer, Scanning Electron Microscope (SEM) and Thermogravimetric Analyser (TGA). The feasibility of FCN to remove total suspended solids (TSS), turbidity, chemical oxygen demand (COD), and, oil and grease (O&G) from POME was investigated using a jar test method. The optimum conditions for contaminant removal from POME were determined by varying the experimental parameters such as flocculant dosage, solution pH and settling time. The results obtained showed that FCN, at a dosage of 1.5 g/L, a contact time of 60 min and pH of 5.0 gave a highest reduction of turbidity, TSS, COD and O&G levels by 72.38%, 77.32%, 71.60% and 53.40%, respectively. Besides that, FCN exhibited a better flocculation performance as compared to alum and chitosan. After three cycles of flocculation/deflocculation process, FCN retained satisfying flocculation efficiency and flocculants recovery in the range of 80-83% and 43.2-78.6%, respectively. Combination of charge neutralisation and polymer bridging was the main key mechanism of interaction between FCN and POME contaminants. The synergy effect between iron oxide/oxyhydroxide nanoparticle and chitosan has increased the physicochemical properties and flocculation performance of the FCN nanocomposite. Overall, FCN nanocomposite can be used an alternative flocculant for POME treatment. 2024, Penerbit UTM Press. All rights reserved.

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