A photocurable method for copper(ii) oxide-doped polyaniline conducting polymer membrane synthesis

Illyas Md Isa

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Type :	article
Subject :	Q Science (General)
ISSN :	0974-1496
Main Author :	Illyas Md Isa
Additional Authors :	Norlaili Abu Bakar
Title :	A photocurable method for copper(ii) oxide-doped polyaniline conducting polymer membrane synthesis

Place of Production :	Tanjung Malim
Publisher :	Fakulti Sains dan Matematik
Year of Publication :	2023
Notes :	Rasayan Journal of Chemistry
Corporate Name :	Universiti Pendidikan Sultan Idris
HTTP Link :	Click to view web link

Abstract : Universiti Pendidikan Sultan Idris

The development of conductive polyaniline (PANI) membrane doped with copper(II) oxide (CuO) by means of the photopolymerization method has been successfully carried out. The photocurable PANI polymeric material was synthesized by mixing 0.011 g of aniline monomer with 0.016 g of ethylene glycol dimethacrylate (EGDMA) crosslinker, 0.021 g of dimethoxy phenylacetophenone (DMPP) photoinitiator and 0.026 g of CuO dopant. The electrical conductivity analysis showed that the as-synthesized CuO-doped PANI (PANI/CuO) film possessed an optimum electrical conductivity value of 39.8110-3 S cm-1 at the dopant loading of 0.011 g CuO. Chemical elucidation by using Fourier-transform infrared spectroscopy (FTIR) revealed that the PANI/CuO conducting material with several main functional groups e.g., N-H, C-H, C-N, C=C, C=N, C-O and C=O chemical bonds were identified. Meanwhile, optical characterization of the resulting PANI/CuO membrane by using UVvis diffuse reflectance spectrophotometer (DR/UV-vis) showed that PANI underwent electron transition ?-?* (C=C) at a wavelength of 324 nm, and band gap values of 2.35 eV, 1.33 eV, 1.39 eV, 1.42 eV, 1.42 eV, and 1.50 eV for PANI, PANI/CuO 0.011 g, PANI/CuO 0.016 g, PANI/CuO 0.021 g, PANI/CuO 0.026 g, and CuO, respectively. 2023, Rasayan Journal of Chemistry, c/o Dr. Pratima Sharma. All rights reserved.

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