UPSI Digital Repository (UDRep)
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Abstract : Perpustakaan Tuanku Bainun |
This study aimed to fabricate and characterise graphene oxide (GO) and reduced GO
(rGO)-based composite nanofiltration (NF) membrane for water treatment
application. Electrochemical exfoliation method assisted by customised triple-tail 1-
butyl-3-imidazolium 1,4-bis(neopentyloxy)-3-(neopentyloxycarbonyl) 1,4-
dioxobutane 2-sulphate (BMIM-TC14) and sodium 1,4-bis(neopentyloxy)-3-
(neopentyloxycarbonyl)-1,4-dioxobutane-2-sulphonate (TC14) surfactants were used
to synthesise GO with N, N-dimethylacetamide (DMAC) used as solvent. Chemical
reduction process utilising hydrazine hydrate was then performed to produce rGO
from GO. Next, GO- and rGO-based composite NF membrane were then fabricated
via non-solvent induced phase separation method utilising DMAC-GO and -rGO,
titanium dioxide (TiO2), multi-walled carbon nanotubes (MWCNTs), polyvinyl
alcohol (PVA), polyvinylpyrrolidone (PVP) and poly (methyl methacrylate) (PMMA)
as additives, while polyvinylidene fluoride (PVDF) and polyethersulfone (PES) were
used as main polymer material. The fabricated NF membranes were then used as
membrane separation for methylene blue (MB) dye removal investigated using deadend
cell filtration system. The findings showed that PVDF/GOTC14/TiO2 composite NF
membrane presented excellent MB dye rejection efficiency (92.63 %) and antifouling
properties (> 100 %) compared to other samples. This was due to the excellent
compatibility between the incorporated hydrophilic additives and PVDF polymer
assisted by triple-tail TC14 surfactant. In conclusion, the fabricated
PVDF/GOTC14/TiO2 showed a potential to be applied as NF membrane material for
dye rejection. Implication of this study is a novel, simpler, low-cost and greener
method for NF membrane fabrication. |
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