UPSI Digital Repository (UDRep)
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UPSI Digital Repository (UDRep)
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| Abstract : Universiti Pendidikan Sultan Idris |
| Impregnation of MgO nanocatalysts on montmorillonite-K10 (MTe) and kinetics studies on transesterification reactions for biodiesel production using Cerbera odollam oil have been conducted. The impregnation process of nanocatalyst into MTe was carried out by mixing the MgO nanocatalyst with MTe dispersed in an ethanol solution. The MgO-MTe product was characterized using X-ray diffraction (XRD), Fourier transform infrared (FT-IR), and scanning electron microscopy (SEM). Transesterification reaction process of Cerbera odollam oil using MgO-MTe catalyst carried out in batch modified-microwave reactor with various oil/methanol ratios, reaction temperatures, reaction time, and the percentage weight of catalyst. Furthermore, the reaction kinetics analysis is done using the pseudo-first-order reaction. The quality of biodiesel was determined using the American society for testing and materials (ASTM) method for biodiesel test. The results show that with the increasing percentage weight of catalysts, product increases with optimum conditions obtained on the weight of catalysts 7% (w/w). Meanwhile, the ratio of oil-to-methanol ration with the optimum yield was obtained at 1:12 at 78 °C with reaction time of 3 h. The reaction kinetics analysis was obtained including k = 2.50 x 10−4 min−1, Ea = 73.43 kJ mol−1 and the pre-exponential factor A = 19.22 min.−1 © 2024 The Authors |
| References |
Agarwal, A.K., Rajamanoharan, K., 2009. Experimental investigations of performance and emissions of Karanja oil and its blends in a single cylinder agricultural diesel engine. Appl. Energy 86, 106–112. https://doi.org/10.1016/j.apenergy.2008.04.008. Ambat, I., Srivastava, V., Haapaniemi, E., Sillanp¨a¨a, M., 2019a. Nano-magneticpotassium impregnated ceria as catalyst for the biodiesel production. Renew. Energy 139, 1428–1436. https://doi.org/10.1016/j.renene.2019.03.042. Ambat, I., Srivastava, V., Haapaniemi, E., Sillanpa¨¨a, M., 2019b. Effect of lithium ions onthe catalytic efficiency of calcium oxide as a nanocatalyst for the transesterification of lard oil. Sustain. Energy Fuels 3, 2464–2474. https://doi.org/10.1039/C9SE00210C. Ameen, M., Ahmad, M., Zafar, M., Munir, M., Mujtaba, M.M., Sultana, S.R., El-Khatib, S. E., Soudagar, M.E.M., Kalam, M.A., 2022. Prospects of catalysis for process sustainability of eco-green biodiesel synthesis via transesterification: a state-of-theart review. Sustainability. https://doi.org/10.3390/su14127032. Ashraful, A.M., Masjuki, H.H., Kalam, M.A., Rizwanul Fattah, I.M., Imtenan, S., Shahir, S. A., Mobarak, H.M., 2014. Production and comparison of fuel properties, engine performance, and emission characteristics of biodiesel from various non-edible vegetable oils: a review. Energy Convers. Manag. 80, 202–228. https://doi.org/10.1016/j.enconman.2014.01.037. Athar, M., Zaidi, S., 2020. A review of the feedstocks, catalysts, and intensification techniques for sustainable biodiesel production. J. Environ. Chem. Eng. 8, 104523 https://doi.org/10.1016/j.jece.2020.104523. Bahulayan, D., Das, S.K., Iqbal, J., 2003. Montmorillonite K10 Clay : an Efficient Catalyst for the One-Pot Stereoselective Synthesis of -Acetamido Ketones Clays are known for their Lewis acid activity and have acquired an important place in synthetic organic chem- istry . 1 Clays have been widely. J. Org. Chem. 68, 5735–5738. Booramurthy, V.K., Kasimani, R., Pandian, S., 2022a. Biodiesel production from tannery waste using a nano catalyst (Ferric-Manganese doped sulphated zirconia). Energy Sources, Part A Recover. Util. Environ. Eff. 44, 1092–1104. https://doi.org/10.1080/15567036.2019.1639849. Booramurthy, V.K., Kasimani, R., Pandian, S., Subramanian, D., 2022b. Magnetic nanocatalyzed synthesis of biodiesel from tannery sludge: characterization, optimization and kinetic studies. Arabian J. Sci. Eng. 47, 6341–6353. https://doi.org/10.1007/s13369-021-06020-9. Bui, H.M., Manickam, S., 2023. Process optimization and environmental analysis of ultrasound-assisted biodiesel production from pangasius fat using CoFe2O4 catalyst. ACS Omega 8, 36162–36170. https://doi.org/10.1021/acsomega.3c04461. Darnoko, D., Cheryan, M., 2000. Kinetics of palm oil transesterification in a batch reactor. JAOCS, J. Am. Oil Chem. Soc. 77, 1263–1267. https://doi.org/10.1007/s11746-000-0198-y. Dugala, N.S., Goindi, G.S., Sharma, A., 2021. Experimental investigations on the performance and emissions characteristics of dual biodiesel blends on a varying compression ratio diesel engine. SN Appl. Sci. 3, 622. https://doi.org/10.1007/s42452-021-04618-0. Feyzi, M., Hosseini, N., Yaghobi, N., Ezzati, R., 2017. Preparation, characterization, kinetic and thermodynamic studies of MgO-La2O3 nanocatalysts for biodiesel production from sunflower oil. Chem. Phys. Lett. 677, 19–29. https://doi.org/10.1016/j.cplett.2017.03.014. Feyzi, M., Shahbazi, Z., 2017. Preparation, kinetic and thermodynamic studies of Al–Sr nanocatalysts for biodiesel production. J. Taiwan Inst. Chem. Eng. 71, 145–155. https://doi.org/10.1016/j.jtice.2016.11.023. Galvan, D., Orives, J.R., Coppo, R.L., Silva, E.T., Angilelli, K.G., Borsato, D., 2013. Determination of the kinetics and thermodynamics parameters of biodiesel oxidation reaction obtained from an optimized mixture of vegetable oil and animal fat. Energy Fuel. 27, 6866–6871. https://doi.org/10.1021/ef401927x. Hasanudin, N., Abd Ghani, N., Ab Rahim, A.H., Azman, N.S., Rosdi, N.A., Masri, A.N., 2022. Optimization and kinetic studies on biodiesel conversion from chlorella vulgaris microalgae using pyrrolidinium-based ionic liquids as a catalyst. Catalysts. https://doi.org/10.3390/catal12030277. Hassan, A.A., Smith, J.D., 2020. Investigation of microwave-assisted transesterification reactor of waste cooking oil. Renew. Energy 162, 1735–1746. https://doi.org/10.1016/j.renene.2020.09.123. Ijaz, A., Anwar, Z., Zafar, M., 2023. Screening of wastewater Oedogonium oblangum algae for hyper-oil transformation into biodiesel by response surface methodology. Kuwait J. Sci. 50, 627–638. https://doi.org/10.1016/j.kjs.2023.03.005. Ikeue, K., Miyamoto, Y., Ando, E., 2023. Metal-substituted layered Fe-based oxides as a solid base catalyst. Chem. Phys. Lett. 830, 140816 https://doi.org/10.1016/j. cplett.2023.140816. Ingle, A.P., Chandel, A.K., Philippini, R., Martiniano, S.E., daSilva, S.S., 2020. Advances in Nanocatalysts Mediated Biodiesel Production: A Critical Appraisal. Symmetry (Basel). https://doi.org/10.3390/sym12020256. Joshi, S.M., Gogate, P.R., Suresh Kumar, S., 2018. Intensification of esterification of karanja oil for production of biodiesel using ultrasound assisted approach with optimization using response surface methodology. Chem. Eng. Process. - Process Intensif. 124, 186–198. https://doi.org/10.1016/j.cep.2017.12.010. Kansedo, J., Sim, Y.X., Lee, K.T., 2019. Feasibility of continuous fatty acid methyl esters (FAME) production from hydrolyzed sea mango (Cerbera odollam) oil at room temperature using cationic ion exchange resin. IOP Conf. Ser. Mater. Sci. Eng. 495, 12050 https://doi.org/10.1088/1757-899X/495/1/012050. Khan, H.M., Iqbal, T., Mujtaba, M.A., Soudagar, M.E.M., Veza, I., Fattah, I.M.R., 2021. Microwave assisted biodiesel production using heterogeneous catalysts. Energies. https://doi.org/10.3390/en14238135. Khedri, B., Mostafaei, M., Safieddin Ardebili, S.M., 2019. A review on microwaveassisted biodiesel production. Energy Sources, Part A Recover. Util. Environ. Eff. 41, 2377–2395. https://doi.org/10.1080/15567036.2018.1563246. Kumar, V., Ramesh, K., Sivakumar, P., Santhosh, V., Sakthi Saravanan, A., Muralidharan, N.G., Yasvanthrajan, N., 2016. Magnetized-nano catalyst KF/CaOFe3O4for biodiesel production from beef tallow. J. Chem. Pharmaceut. Sci. 9, 193–195. Li, J., Peng, X., Luo, M., Zhao, C.J., Gu, C.B., Zu, Y.G., Fu, Y.J., 2014. Biodiesel production from Camptotheca acuminata seed oil catalyzed by novel Bronsted-Lewis ¨ acidic ionic liquid. Appl. Energy 115, 438–444. https://doi.org/10.1016/j.apenergy.2013.10.025. Ma, Y., Wang, Q., Sun, X., Wu, C., Gao, Z., 2017. Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst. Renew. Energy 107, 522–530. https://doi.org/10.1016/j.renene.2017.02.007. Mguni, L., Meijboom, R., Jalama, K., 2012. Biodiesel production over nano-MgO supported on titania. Proc. World Acad 5592367, 1155–1159. Muanruksa, P., Winterburn, J., Kaewkannetra, P., 2019. A novel process for biodiesel production from sludge palm oil. MethodsX 6, 2838–2844. https://doi.org/10.1016/j.mex.2019.09.039. Mustafa, K., Iqbal, N., Fan, X., Farrukh, S., Musaddiq, S., 2022. Synthesis, characterization and applications of solid-based heterogeneous nanocatalysts for biodiesel production. In: Heterogeneous Nanocatalysis for Energy and Environmental Sustainability, pp. 91–110. https://doi.org/10.1002/9781119772057.ch3. Nandiwale, K.Y., Bokade, V.V., 2014. Process optimization by response surface methodology and kinetic modeling for synthesis of methyl oleate biodiesel over H3PW12O40 anchored montmorillonite K10. Ind. Eng. Chem. Res. 53, 18690–18698. https://doi.org/10.1021/ie500672v. |
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