Ionothermal synthesis and characterization of CoAPO-34 molecular sieve

Mazlina Musa

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Type :	article
Subject :	Q Science (General)
Main Author :	Mazlina Musa
Additional Authors :	M. Dawson, Daniel Ashbrook, Sharon E. Morris, Russell E.
Title :	Ionothermal synthesis and characterization of CoAPO-34 molecular sieve

Place of Production :	CrossMark
Year of Publication :	2017

Abstract :

The cobalt-doped aluminophosphate molecular sieve, CoAPO-34 (with the chabazite-type topology) was prepared under ionothermal conditions using 1-ethyl-3-methylimidazolium bromide (EMIMBr) ionic liquid in presence of 1,6-hexanediamine (HDA). The HDA is not incorporated in CoAPO-34, but is required to mediate the availability of Co2þ during the synthesis. The material was characterized using powder Xray diffraction (PXRD), thermogravimetric analysis (TGA) and solid-state NMR spectroscopy. Wideline 31P NMR spectroscopy showed broad signals (~5000e10000 ppm wide), confirming that paramagnetic cobalt ions are successfully incorporated within the framework of the materials.

References

[1] A. Corma, Chem. Rev. 95 (1995) 559e614. [2] E. Davis, Chem. Mater. 4 (1992) 756e768. [3] E.R. Cooper, C.D. Andrews, P.S. Wheatley, P.B. Webb, P. Wormald, R.E. Morris,Nature 430 (2004) 1012e1016. [4] E.R. Parnham, R.E. Morris, Acc. Chem. Res. 40 (2007) 1005e1013. [5] J.M. Griffin, L. Clark, V.R. Seymour, D.W. Aldous, D.M. Dawson, D. Iuga,R.E. Morris, S.E. Ashbrook, Chem. Sci. 3 (2012) 2293e2300. [6] Y. Wei, Z. Tian, H. Gies, R. Xu, H. Ma, R. Pei, W. Zhang, Y. Xu, L. Wang, K. Li, B. Wang, G. Wen, L. Lin, Angew. Chem. Int. Ed. 49 (2010) 5367e5370. [7] H. Xing, Chem. Mater. 20 (2008) 4179e4181. [8] R.P. Bontchev, Chem. Mater. 9 (1997) 3155e3158. [9] E.R. Parnham, R.E. Morris, J. Am. Chem. Soc. 128 (2006) 2204e2205. [10] E.A. Drylie, D.S. Wragg, E.R. Parnham, P.S. Wheatley, A.M.Z. Slawin,J.E. Warren, R.E. Morris, Angew. Chem. Int. Ed. 46 (2007) 7839e7843. [11] D. Li, Y. Xu, Y. Wang, H. Liu, B. Wang, H. Ma, R. Xu, Z. Tian, Micropor. Mesopor.Mater. 198 (2014) 153e160. [12] S.J. Hill, C.D. Williams, C.V.A. Duke, Zeolites 17 (1996) 291e296. [13] N. Raji�c, A. Risti�c, A. Tuel, V. Kaucic, Zeolites 18 (1997) 115e118. [14] Z. Yan, B. Chen, Y. Huang, Solid State Nucl. Magn. Reson. 35 (2009) 49e60. [15] L. Marchese, E. Gianotti, B. Palella, R. Pirone, G. Martra, S. Coluccia,P. Ciambelli, Stud. Surf. Sci. Catal. 130 (2000) 3005e3010. [16] S. Oh, W. Lee, Kor. J. Chem. Eng. 9 (1992) 37e44. [17] E.R. Parnham, R.E. Morris, Chem. Mater. 18 (2006) 4882e4887. [18] Y.Y. Tong, J. Magn. Reson. A 119 (1996) 22e28. [19] A. Tuel, S. Caldarelli, A. Meden, L.B. McCusker, C. Baerlocher, A. Ristic, G. Mali, V. Kaucic, J. Phys. Chem. B 104 (2000) 5697e5705. [20] A. Risti�c, N.N. Tusar, I. Arcon, F.T. Starzyk, D. Hanzel, J. Czyzniewska, V. Kaucic, Micropor. Mesopor. Mater. 56 (2002) 303e315. [21] N.N. Tusar, V. Kaucic, S. Geremia, G. Vlaic, Zeolites 15 (1995) 708e713. [22] B. Chen, Y. Huang, Micropor. Mesopor. Mater. 123 (2009) 71e77. [23] S.H. Chen, S.P. Sheu, K.J. Chao, J. Chem. Soc. Chem. Commun. (1992) 1504e1505. [24] S. Thomson, V. Luca, R. Howe, Phys. Chem. Chem. Phys. 1 (1999) 615e619. [25] J. Chen, G. Sankar, J.M. Thomas, R. Xu, G.N. Greaves, D. Waller, Chem. Mater. 4(1992) 1373e1380. [26] C. Montes, M.E. Davis, B. Murray, M. Narayana, J. Phys. Chem. 94 (1990) 6425e6430. [27] S. Sneddon, Ph.D. Thesis, University of St Andrews, St Andrews, UK, (2015). [28] M.P.J. Peeters, J.W. de Haan, L.J.M. van de Ven, J.H.C. van Hooff, Coll. Surf. A 72 (1993) 87e104. [29] B.K. Czarnetzki, W.G.M. Hoogervorst, R.R. Andrea, C.A. Emeis, W.H.J. Stork, J. Chem. Soc. Faraday Trans. 87 (1991) 891e895. [30] L. Canesson, A. Tuel, Chem. Commun. (1997) 241e242. [31] G. Mali, A. Risti�c, V. Kau�ci�c, J. Phys. Chem. B 109 (2005) 10711e10716. [32] M.T. Sananes, A. Tuel, J. Chem. Soc. Chem. Commun. (1995) 1323e1324. [33] M.T. Sananes, A. Tuel, Solid State Nucl. Magn. Reson. 6 (1996) 157e166. [34] M.T. Sananes, A. Tuel, G.J. Hutchings, J.C. Volta, J. Catal. 148 (1994) 395e398. [35] J. Chen, S. Natarajan, J.M. Thomas, R.H. Jones, M.B. Hursthouse, Angew. Chem. Int. Ed. 33 (1994) 639e640.

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