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Type :article
Subject :Q Science (General)
Main Author :Shakinaz Desa
Additional Authors :Asaad Abbas
Title :Agricultural waste biodiesel potential and physicochemical properties in extracted seeds oil
Place of Production :Tanjong Malim
Publisher :Fakulti Sains dan Matematik
Year of Publication :2019
Corporate Name :Universiti Pendidikan Sultan Idris

Abstract : Universiti Pendidikan Sultan Idris
Biodiesel is one of the best available resources that have come to the forefront recently. Malaysia has an abundance of agricultural waste which can be tapped as one of the biodiesel resources. This study aimed at evaluating the appropriate Techniques of drying the plant seeds from the agricultural waste in terms of quantity extract of the oils from seed by using Soxhlet with solvent n-hexane, we compared biodiesel potential between seed oil extracted from Mango kernel (Mangifera indica), Rambutan (Nephelium lappaceum),Pumpkin (Cucurbita ps) and Papaya (Carica Papaya. L). we examined the oil physicochemical properties. In order to establish an optimum condition for the production of biodiesel, parameters such as catalyst loading, reaction temperature, methanol to oil molar ratio were studied. The results analyzed revealed that the transesterification of the Nephelium Lappaceu oil, the condition of the optimum reaction was found to be 65oC reaction temperature, 12:1 molar ratio of methanol to oil, 2.0% catalyst (w/w) and an hour reaction time. The optimum reaction conditions for Cucurbita oil were also found to be 65oC reaction temperature, 12:1 molar ratio of methanol to oil, 2.0% catalyst (w/w) and reaction time of 1hr. These conditions gave an ester (Cucurbita spoil methyl ester) yield of 96.81% by weight; it is the best yield from between the study oils. The properties of biodiesel have characterized the results were found to satisfy a standard of EN14214 and ASTM D6751.The research findings marked all seed oils in this paper as a promising resource for biodiesel production.

References

[1] G. Abdulkareem-Alsultan, N. Asikin-Mijan, H.V. Lee, Y.H. Taufiq-Yap, A new route for the synthesis of La-Ca oxide supported on nano activated carbon via vacuum impregnation method for one pot esterification-transesterification reaction, 2016. doi:10.1016/j.cej.2016.05.116.

[2] M.H. Mosarof, M.A. Kalam, H.H. Masjuki, A.M. Ashraful, M.M. Rashed, H.K. Imdadul, I.M. Monirul, Implementation of palm biodiesel based on economic aspects ,performance ,emission , and wear characteristics, Energy Convers. Manag. 105 (2015) 617–629. doi:10.1016/j.enconman.2015.08.020.

[3] Sabiiti, E. N., Bareeba, F. B., Sporndly, E., Tenywa, J. S., Ledin, S., Ottabong, E., ... & Drake, L. (2004). Urban market garbage: a hidden resource for sustainable urban/peri-urban agriculture and the environment in Uganda

[4] J. Kansedo, K.T. Lee, S. Bhatia, Cerbera odollam (sea mango) oil as a promising non-edible feedstock for biodiesel production, Fuel. 88 (2009) 1148–1150. doi:10.1016/j.fuel.2008.12.004.

[5] J. Kansedo, K.T. Lee, Process optimization and kinetic study for biodiesel production from non-edible sea mango (Cerbera odollam) oil using response surface methodology, Chem. Eng. J. 214 (2013) 157–164. doi:10.1016/j.cej.2012.10.048.

[6] B. Mahisanunt, K. Na Jom, S. Matsukawa, U. Klinkesorn, Solvent fractionation of rambutan (Nephelium lappaceum L.) kernel fat for production of non-hydrogenated solid fat: Influence of time and solvent type, J. King Saud Univ. - Sci. 29 (2017) 32–46. doi:10.1016/j.jksus.2016.08.004.

[7] W.S.C. Mei, A. Ismail, N.M. Esa, G.A. Akowuah, H.C. Wai, Y.H. Seng, The Effectiveness of Rambutan (Nephelium lappaceum L.) Extract in Stabilization of Sunflower Oil under Accelerated Conditions, Antioxidants. 3 (2014) 371–386. doi:10.3390/antiox3020371.

[8] Malacrida, C. R., Kimura, M., & Jorge, N. (2011). Characterization of a high oleic oil extracted from papaya (Carica papaya L.) seeds. Food Science and Technology, 31(4), 929-934.

[9] Gohari Ardabili, A., Farhoosh, R., & Haddad Khodaparast, M. H. (2011). Chemical composition and physicochemical properties of pumpkin seeds (Cucurbita pepo Subsp. pepo Var. Styriaka) grown in Iran. Journal of Agricultural Science and Technology, 13, 1053-1063.

[10] N. Asikin-Mijan, H.V. Lee, Y.H. Taufiq-Yap, G. Abdulkrem-Alsultan, M.S. Mastuli, H.C. Ong, Optimization study of SiO2-Al2O3 supported bifunctional acid–base NiO-CaO for renewable fuel production using response surface methodology, Energy Convers. Manag. (2016). doi:10.1016/j.enconman.2016.09.041.

[11] N. Mansir, S.H. Teo, U. Rashid, M.I. Saiman, Y.P. Tan, G.A. Alsultan, Y.H. Taufiq-Yap, Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review, Renew. Sustain. Energy Rev. (2017). doi:10.1016/j.rser.2017.10.098.

[12] S.K. Narwal, R. Gupta, Biodiesel production by transesterification using immobilized lipase, Biotechnol. Lett. 35 (2013) 479–490. doi:10.1007/s10529-012-1116-z.

[13] Guil-Laynez, J. L., Guil-Guerrero, J. L., & Guil-Laynez, Á. (2019). Bioprospecting for seed oils in tropical areas for biodiesel production. Industrial Crops and Products, 128, 504-511.

[14] Razavi, R., Bemani, A., Baghban, A., Mohammadi, A. H., & Habibzadeh, S. (2019). An insight into the estimation of fatty acid methyl ester based biodiesel properties using a LSSVM model. Fuel, 243, 133-141.

[15] Almutairi, A., Wu, D., Guo, B., Roskilly, A. P., & Ottley, C. (2017). Characterization of lubricant degeneration and component deterioration on diesel engine fueling with straight plant oil. Energy Procedia, 105, 636-641.

[16] Gunstone, F. D. (Ed.). (2004). Rapeseed and canola oil: production, processing, properties and uses. CRC Press.

[17] Rodenbush, C. M., Hsieh, F. H., & Viswanath, D. S. (1999). Density and viscosity of vegetable oils. Journal of the American Oil Chemists' Society, 76(12), 1415-1419.

[18] Elangovan, T., Anbarasu, G., & Jeryrajkumar, L. (2016). Development of Calophyllum inophyllum biodiesel and analysis of its properties at different blends. International Journal of ChemTech Research, 9(4), 220-229.

[19] Pramanik, K. "Properties and use of Jatropha curcas oil and diesel fuel blends in compression ignition engine." Renewable energy 28, no. 2 (2003): 239-248.

[20] Banapurmath, N. R., Tewari, P. G., & Hosmath, R. S. (2008). Performance and emission characteristics of a DI compression ignition engine operated on Honge, Jatropha and sesame oil methyl esters. Renewable energy, 33(9), 1982-1988.

[21] Ibeto, C. N., Okoye, C. O. B., & Ofoefule, A. U. (2012). Comparative study of the physicochemical characterization of some oils as potential feedstock for biodiesel production. ISRN Renewable Energy, 2012.

[22] Leung, D. Y. C., & Guo, Y. (2006). Transesterification of neat and used frying oil: optimization for biodiesel production. Fuel processing technology, 87(10), 883-890.

[23] Encinar, J. M., Gonzalez, J. F., & Rodríguez-Reinares, A. (2005). Biodiesel from used frying oil. Variables affecting the yields and characteristics of the biodiesel. Industrial & Engineering Chemistry Research, 44(15), 5491-5499.

[24] Srivastava, A., & Prasad, R. (2000). Triglycerides-based diesel fuels. Renewable and sustainable energy reviews, 4(2), 111-133.

[25] [25] Ma, F., Clements, L. D., & Hanna, M. A. (1999). The effect of mixing on transesterification of beef tallow. Bioresource Technology, 69(3), 289-293.

[26] Van Gerpen, J. (2005). Biodiesel processing and production. Fuel processing technology, 86(10), 1097-1107.

[27] Knothe, G. (2002). Structure indices in FA chemistry. How relevant is the iodine value?. Journal of the American Oil Chemists' Society, 79(9), 847-854.

[28] Canakci, M., & Van Gerpen, J. (1999). Biodiesel production viaacid catalysis. Transactions of the ASAE, 42(5), 1203.

[29] Krishnakumar, U., Sivasubramanian, V., & Selvaraju, N. (2013). Physico-chemical properties of the biodiesel extracted from rubber seed oil using solid metal oxide catalysts. International Journal of Engineering Research and Applications, 3(4), 2206-2209.

[30] Rashid, U., & Anwar, F. (2008). Production of biodiesel through optimized alkaline-catalyzed transesterification of rapeseed oil. Fuel, 87(3), 265-273.

[31] Sebayang, D., Agustian, E., & Praptijanto, A. (2010). Transesterification of biodiesel from waste cooking oil using ultrasonic technique.

[32] Takase, M., Zhang, M., Feng, W., Chen, Y., Zhao, T., Cobbina, S. J., ... & Wu, X. (2014). Application of zirconia modified with KOH as heterogeneous solid base catalyst to new non-edible oil for biodiesel. Energy conversion and management, 80, 117-125.

 


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