UPSI Digital Repository (UDRep)
Start | FAQ | About

Structure and Physical Properties of 30MgSO4-(70-x) P2O5-xSm2O3 glasses

AVAILABLE Article 880 Views
Back to search
Scan QR Code to share or view item link:

Digital Assets & Download Files
Login required to access this item.
General Information Cached
Title
Structure and Physical Properties of 30MgSO4-(70-x) P2O5-xSm2O3 glasses
Type
Article
Main Author
Aliyu Mohammed Aliyu
Additional Authors
  • N.E. Ahmed
Subject
Q Science (General)
Language Code
eng
Bibliographic Details
Place of Production
Tanjong Malim
Publisher
Fakulti Sains dan Matematik
Year of publication
2019
Degree Type
Others
Corporate Name
Universiti Pendidikan Sultan Idris

Abstract

Glassesin  the  series  30MgSO4-(70-x)  P2O5-xSm2O3 0.2 ≤x≤1.0  mol  percentwere  prepared  by  single  step melt-quenchtechniques,   thestructure,   physicalandoptical propertiesofsamarium   oxide   at   different concentrationswere   studied.The   amorphous phase   of   the   samples   was   verifiedby   X-ray   diffraction spectroscopy,  the  structural  units  were  investigated  using  Fourier Transform  Infrared, Raman  and  NMR spectroscopy where the spectra revealthe presence of symmetric, asymmetric, torsoionalandbending vibration of phosphate groups,the NMR spectra reveals the changes in Qndistributionhere discussed,thecompositional dependenceonphysical (density,  average  molar  weight,dielectric  constant,Inter-nuclear  distance, Field strength,Molar volume, Molar refractivity  etc) and optical  parameterswere determined. In  terms  of  structural modifications, there  is variation of density and molar volume, the  glass sample  hasincreasing refractive  index values  with  decreasing  molar  volume content.  The  luminescence  spectra  were  observed  within UV-Vis-NIR region,  the  absorption  spectra  of  the  sample  were  recorded  in  the  range  of  350  to  1800  nm  meanwhile, absorption edge the optical band-gap,and ?E wasevaluated. Our result may be advantageousfor many optical applications (e.g visible lasers or color displays).  

References

[1] M.  Abid,  M.  Et-tabirou,  M.  Taibi, Structure  and  DC  conductivity  of  lead  sodium  ultraphosphate glasses, Mater. Sci. Eng.B 97 (2003) 20-24

[2] S.F.  Ismail,  M.R.  Sahar,  S.K.  Ghoshal,  Physical  and  absorption  properties  of  titanium  nano-particles incorporated into zinc magnesium phosphate glass, Mater. Charact.111 (2016) 177-182

[3] R.  Praveena,  V.  Venkatramu,  P.  Babu,  C.K.  Jayasankar,  Fluorescence  spectroscopy  of  Sm3+ions  in P2O5-PbO-Nb2O5glasses, Physica B403 (2008) 3527-3534

[4] Bin  Qian,  Xiaofeng  Liang,  Shiyuan  Yang, Shu  He,  Long  Gao.Effects  of  lanthanum  addition  on  the structure and properties of iron phosphate glasses, J. Mol. Struct.1027 (2012) 31-35

[5] Toshinori  Okura,  Tomoko  Miyachi,  Hideki  Monma, Properties  and  vibrational  spectra  of  magnesium phosphate glasses for nuclear waste immobilization, J. Eur. Ceram. Soc.26 (2006)831-836

[6]N. Sooraj Hussain, M.A. Lopes, J.D. Santos,A comparative study of CaO-P2O5-SiO2 gels preparedby a sol-gel method, Mater. Chem. Phys88 (2004) 5-8

[7] Yasser  B.  Saddeek,  Network  structure  of  molybdenum  lead  phosphate  glasses:  Infrared  spectra  and constants of elasticity, Physica B406 (2011) 562-566

[8] Daniela Carta, David M. Pickup, Jonathan C. Knowles, I. Ahmed, Mark E. Smith, Robert J. Newport, A  structural  study  of  sol-gel  and  melt-quenched  phosphate-based  glasses,  J.  Non-Cryst.  Solids  353 (2007) 1759-1765

[9] R.Hussin,  Muhammad  Shawal  Husin,  Dayang  Nur  Fazliana  Abdul  Halimand  Sinin  Hamdan, Vibrational studies  of  crystalline  phase  strontium  magnesium  phosphates  doped  with  Eu2O3,Adv.Mater. Res. 18 (2010) 288-301

[10]F Ahmadi1,R Hussin and S K Ghoshal, Structural and physical properties of Sm3+doped magnesium zinc sulfophosphate glass, Bull. Mater. Sci,40 (2017) 1097-1104

[11] A.  M.Aliyu,  R.  Hussin,  Karim  Deraman,  N.  E.  Ahmad, Amina  M.  Danmadami,  Y.  A. Yamusa, Physical and optical properties of calcium sulfate ultra-phosphate glass-doped Er2O3, Int. J. M. P. B,32(2018) 1-14

[12] M.A.  Karakassides,  A.  Saranti,  I.  Koutselas,  Preparation  and  structural  study  of  binary  phosphate glasseswith high calcium and/or magnesium content, J. Non-Cryst.Solids 347 (2004) 69-79

[13]G. Walter, J. Vogel, U. Hoppe, P. Hartmann, Structural study of magnesium polyphosphate glasses, J. Non-CrystSolids 320 (2003) 210-222

[14] E.  Matsubara,  Y.  Waseda,  M.  Ashizuka,  E.  Ishida,  Structural  study  of  binary  phosphate  glasses  with MgO,ZnO, and CaO by X-ray diffraction, J. Non-Cryst. Solids 103 (1988) 117-124

[15]Yasser  Saleh  Mustafa  Alajerami,  Suhairul  Hashim,  Wan  Muhamad  Saridan  Wan  Hassan,  Ahmad Termizi Ramli,  Azman  Kasim,  Optical  properties  of  lithium  magnesium  borate  glasses  doped  with Dy3+and Sm3+ions, Physica B407 (2012) 2398-2403

[16] Simon  Striepe,  Ning  Da,  Joachim  Deubener,  Lothar  Wondraczek,  Micromechanical  properties  of (Na,Zn)-sulfophosphate glasses, J. Non-Cryst.Solids 358 (2012) 1032-1037

[17] Arnulf  Thieme,  Doris Möncke,  René  Limbach,  Sindy  Fuhrmann,  Efstratios  I.  Kamitsos,  Lothar Wondraczek, Structure and properties of alkali and silver sulfophosphate glasses, J. Non-Cryst.Solids 410 (2015) 142–150

[18]T.G.V.M. Rao, A.Rupesh Kumar, N. Veeraiah, M.Rami Reddy, Optical and structural investigation of Sm3+–Nd3+co-doped  in  magnesium  lead  boro-silicate  glasses, J.  Phy.  Chem.  Solids74  (2013)  410–417

[19]P.  RaghavaRao,  G.MuraliKrishna,M.G.Brik,  Y.Gandhi,  N.Veeraiah.Fluorescence  features  of  Sm3+ions inNa2SO4-MO-P2O5glass system Influence of modifier oxide, J. lumin.131 (2011) 212-217

[20]Z. Mazurak, S. Body?, R. Lisiecki, J. Gabrys ?-Pisarska, M. Czaja, Optical properties of Pr3+, Sm3+and Er3+doped P2O5-CaO-SrO-BaO phosphate glass, Opt. Mater.32 (2010) 547-553

[21]C.R.  Kesavulu,  C.K.  Jayasankar,  White  light  emission  in  Dy3+-doped  lead  fluorophosphate  glasses, Mater. Chem. Phy.130 (2011) 1078 -1085

[22] Ki-Soo  Lim,  N.  Vijaya,  C.R.  Kesavulu,  C.K.  Jayasankar,  Structural  and  luminescence  properties  of Sm3+ions in zinc fluorophosphate glasses, Opt. Mater.35 (2013) 1557-1563

[23] V.Venkatramu,   P.   Babu,  C.K.   Jayasankar,   Th.   Tro ?  ster,   W.   Sievers,   G.   Wortmann,   Optical spectroscopy of Sm3+ions in phosphate and fluorophosphate glasses, Opt. Mater. 29 (2007) 1429-1439

[24]P.   Chimalawong,   J.Kaewkhao,   C.Kedkaew,   P.Limsuwan,   Optical   and   electronic   polarizability investigationof Nd3+-doped soda-lime silicate glasses, J. Phy. Chem. Solids71 (2010) 965-970

[25]C.  Dayanand,  G.  Bhikshamaiah,  V.  Jayatyagaraju,  M.  Salagram,  Review  structural  investigations  of phosphate glasses: a details infrared study of the x (PbO)-(1-x) P2O5vitreous system, J Mater Sci31 (1996) 1945-1967

[26] A. A. Higazy and B. Brigde, Infrared spectra of vitreous system Co3O4-P2O5and their interpretation,J Mater Sci20 (1985) 2345-2358

[27]H. Doweidar, Y.M. Moustafa, K. El-Egili,  I. Abbas, Infrared spectra  of Fe2O3-PbO-P2O5glasses, Vib Spectrosc37 (2005) 91-96

[28]M.  Sherief.  Abo-Naf,  N.  A.  Ghoneim,  H.  A.  El-Batal,  Preparation  and  characterization  of  Sol-gel derived glasses in the ternary Na2O-Al2O3-P2O5system,J. Mater. Sci-Mater El, 15 (2004) 273-282

[29]L.  Baia,  D.  Muresan,  M.  Baia,  J.  Popp,  S.  Simon, Structural  properties  of  silver  nano-clusters phosphateglass composite, Vib. Spectrosc.43 (2007) 313-318

[30]M. Hafid, T. Jermoumi, N. Toreis, T. Ghailassi, Structure of (45-x) Na2O-xBaO-5ZnO-50P2O5glasses studied by DSC and infrared spectroscopy, Mate. Lett,56 (2002) 486-490

[31]P.  Raghava  Rao, L. Pavi?, A. Moguš-Milankovi?, V. Ravi Kumar, I.V. Kityk, N. Veeraiah, Electrical and spectroscopic properties of Fe2O3doped Na2SO4-BaO-P2O5glass system, J. Non-Cryst.Solids 358 (2012) 3255-3267

 

[32]J. Schwarz, H. Tichá, L. Tichý,  R. Mertens, Physical properties of PbO-ZnO-P2O5glasses I. Infrared and Raman spectra,J.Optoelectron.Adv.M, 6 (2004) 737 -746

[33] R. K. Brow, R. J. Kirkpatrick, & G. L. Turner, The short range structure of sodium phosphate glasses I. MAS NMR studies. J. Non-Cryst Solids,116(1990)39-45.

[34]H.  Aguiar,  E.L.  Solla,  J.  Serra,  P.  González,  B.  León,  F.  Malz,  C.  Jäger,Raman  and  NMR  study  of bioactive Na2O–MgO–CaO–P2O5–SiO2glasses, J. Non-CrystSolids 354 (2008) 5004–5008

[35] R.  K.  Brow,  D.  R.  Tallant,  J.  J.  Hudgens,  S.  W.  Martin,  &  A.  D.  Irwin,  The short-range  structure  of sodium ultraphosphate glasses. J. Non-CrystSolids,177(1994)221-228.

[36]M.  F.  Faznny,  M.  K.  Halimah,  M.  N  Azlan,Effect  of  lanthanum  oxide  on  optical  properties  of  zincboro-tellurite glass system,J. OptoelectronBioMater8 (2016) 49 -59

[37] S.  Mohan, K. S. Thind, and G. Sharma, Effect of Nd3+Concentration on the  Physical  and Absorption Properties of Sodium-Lead-Borate Glasses,Brazil J. Phy, 37(2007) 1306-1313

[38]K.  El-Egili,  H.  Doweidar,  Y.M.  Moustafa,  I.  Abbas,  Structure  and  some  physical  properties  of  PbO–P2O5,Physica B 339 (2003) 237–245

[39]T.  Suhasini,  J.  Suresh  Kumar,  T.  Sasikala,  Kiwan  Jang,  Ho  Sueb  Lee,  M.  Jayasimhadri,  Jung  Hyun Jeong,Soung  Soo  Yi,  L.  Rama  Moorthy,  Absorption  and  fluorescence  properties  of  Sm3+ ions  in fluoride containing phosphate glasses, Opt. Mater.31 (2009) 1167–1172

[40]W. Carnall, P. Fields and K. Rajnak, Electronic energy levels in the trivalentlanthanides Aquo ionsI. Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+, and Tm3+J. Chem. Phys. 49 (1968) 4424-4442

[41]S. Surendra Babu, P. Babu, C.K. Jayasankar, Th. Tröster, W. Sievers, G. Wortmann, Optical properties ofDy3+doped phosphate and fluorophosphate glasses, Opt. Mater.31 (2009) 624–631

[42]Manal   Abdel-Baki,   F.A.   Abdel-Wahab,   Amr   Radi,   Fouad El-Diasty,   Factors   affecting   optical dispersion in borate glass systems, J. Phy. Chem. Solids 68 (2007) 1457-1470

[43]S.  Sindhu, Sanghi S., Argawal A., Sonam S.V.P., Kishore N, The role of V2O5in the modification of structural, optical and electrical properties of vanadium barium borate glasses,Physica B, 365 (2005), 65

[44]A.  Awang,  S.K.  Ghoshal,  M.R.  Sahar,  M.  Reza  Dousti,  Raja  J.  Amjad,  Fakhra  Nawaz,  Enhanced spectroscopic  properties  and  Judd-Ofelt  parameters  of  Er-doped  tellurite  glass: Effect  of  gold  nano-particles,Curr Appl Phys13 (2013) 1813-1818

[45]M.H.A.Mhareb,   S.Hashim,   S.K.Ghoshal,   Y.S.M.Alajerami,   M.J.Bqoor,   A.I.Hamdan,   M.A.Saleh, M.K.B.AbdulKarim,  Effect  ofDy2O3impurities  on  the  physical,  optical  and  thermo-luminescence properties of lithium borate glass, J. Lumin. 177(2016)366-372

[46] N. Sharmin,  &  C.  D.  Rudd,  Structure,  thermal  properties,  dissolution  behaviour  and  biomedical applications of phosphate glasses and fibres: a review. J. Mater Sci 52 (2017) 8733-8760

[47]A.V. Ravi Kumar, Ch. Srinivasa Rao, T. Srikumar, Y. Gandhi, V. Ravi Kumar, N. Veeraiah,Dielectric dispersion   and   spectroscopic   investigations   on   Na2SO4–B2O3–P2O5glasses   mixed   with   low concentrations of TiO2,J. of Alloys Compd. 515 (2012) 134–142

This material may be protected under Copyright Act which governs the making of photocopies or reproductions of copyrighted materials.
You may use the digitized material for private study, scholarship, or research.
Back to search
Installed and configured by Bahagian Automasi, Perpustakaan Tuanku Bainun, Universiti Pendidikan Sultan Idris
If you have enquiries, kindly contact us at pustakasys@upsi.edu.my or 016-3630263. Office hours only.