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Type :article
Subject :Q Science (General)
Main Author :Fouad Warid
Additional Authors :Ismail Zainol
Nada Mutter Abbass
Nurulsaidah Rahim
Majhool, Alhussen Arkan
Title :Catalysis deoxygenation and hydrodeoxygenation of edible and inedible oil to green fuel
Place of Production :Tanjong Malim
Publisher :Fakulti Sains dan Matematik
Year of Publication :2020
Corporate Name :Universiti Pendidikan Sultan Idris

Abstract : Universiti Pendidikan Sultan Idris
Green diesel or known as the hydrocarbons (alkane and alkene) is a renewable and globally friendly biofuel which generally was derived from the triglycerides or fatty acids. The sustainability of the green diesel always concerned the cost of the production, energy supply and demand (net energy balance), the sustainability of more significant crops production or feedstock supply, acceptance of the country and economic stability. Above all, the lack of the petroleum products, the increase in fuel efficiency and affordable by the public are significant reasons for the green diesel to become one of the most important energy supplies for our future The review found important research areas to be reduction in cost of production and maintenance, improvement in fuel quality and improvement in the environmental benefit from using green diesel. With regard to cost reduction, experiments have been conducted on use of low cost catalysts, waste products as feedstocks and H2-free reaction atmosphere. Fuel quality improvement studies have proposed new catalysts, reaction pathways and conditions to improve hydrocarbon selectivity and fuel stability. Future studies must specifically focus on commercial feasibility of the use of waste materials as feedstocks, heterogeneous catalysts, improvement in reaction pathways to production green diesel and similar other concerns. This article covers the catalysis for deoxygenation, the factor influencing the deoxygenation process and the recent progress of deoxygenation.  

References

[1] Albazzaz, Ahmed Shamil, Abdulkareem GhassanAlsultan, Salmiaton Ali, Yun Hin Taufiq-Yaq, Mohamad Amran Mohd Salleh, and Wan Azlina Wan Abdul Karim Ghani. "Carbon Monoxide Hydrogenation on Activated Carbon Supported Co-Ni Bimetallic Catalysts Via Fischer-Tropsch Reaction to Produce Gasoline." Journal of Energy, Environmental & Chemical Engineering 3, no. 3 (2018): 40. https://doi.org/10.11648/j.jeece.20180303.11

[2] Abdulkareem-Alsultan, G., N. Asikin-Mijan, H. V. Lee, Umer Rashid, Aminul Islam, and Y. H. Taufiq-Yap. "A Review on Thermal Conversion of Plant Oil (Edible and Inedible) into Green Fuel Using Carbon-Based Nanocatalyst." Catalysts 9, no. 4 (2019): 350. https://doi.org/10.3390/catal9040350

[3] Alsultan, Abdulkreem, Asikin Mijan, and Yun Hin Taufiq-Yap. "Preparation of activated carbon from walnut shell doped la and Ca catalyst for biodiesel production from waste cooking oil." In Materials Science Forum, vol. 840, pp. 348-352. Trans Tech Publications Ltd, 2016. https://doi.org/10.4028/www.scientific.net/MSF.840.348

[4] Gupta, Ashwani K., Ashoke De, Suresh K. Aggarwal, Abhijit Kushari, and Akshai Runchal, eds. Innovations in Sustainable Energy and Cleaner Environment. Springer, 2020. https://doi.org/10.1007/978-981-13-9012-8

[5] Samsudin, M. S. N. B. M. M. S. N. B., Rahman, M. M., & Wahid, M. A. (2016). Sustainable power generation pathways in Malaysia: Development of long-range scenarios. Journal of Advanced Research in Applied Mechanics, 24, 22-38.

[6] Lamsal, Buddhi P., and R. D. Tyagi. "Bioenergy and biofuel from biowastes and biomass." American Society of Civil Engineers, 2010. https://doi.org/10.1061/9780784410899

[7] Ibrahim, S. Fadhilah, N. Asikin-Mijan, M. Lokman Ibrahim, G. Abdulkareem-Alsultan, Saiman Mohd Izham, and Y. H. Taufiq-Yap. "Sulfonated functionalization of carbon derived corncob residue via hydrothermal synthesis route for esterification of palm fatty acid distillate." Energy Conversion and Management 210 (2020): 112698. https://doi.org/10.1016/j.enconman.2020.112698

[8] Ko, C. H., Park, S. H., Jeon, J. K., Suh, D. J., Jeong, K. E., & Park, Y. K. (2013). Upgrading of biofuel by the catalytic deoxygenation of biomass. News & Information for Chemical Engineers, 31(1), 135

[9] Asikin-Mijan, N., J. M. Ooi, G. AbdulKareem-Alsultan, H. V. Lee, M. S. Mastuli, Nasar Mansir, Fahad A. Alharthi, Abdulaziz Ali Alghamdi, and Y. H. Taufiq-Yap. "Free-H2 deoxygenation of Jatropha curcas oil into cleaner dieselgrade biofuel over coconut residue-derived activated carbon catalyst." Journal of Cleaner Production 249 (2020): 119381. https://doi.org/10.1016/j.jclepro.2019.119381

[10] Asikin-Mijan, Nurul, Hwei Voon Lee, Joon Ching Juan, A. R. Noorsaadah, G. Abdulkareem-Alsultan, M. Arumugam, and Yun Hin Taufiq-Yap. "Waste clamshell-derived CaO supported Co and W catalysts for renewable fuels production via cracking-deoxygenation of triolein." Journal of Analytical and Applied Pyrolysis 120 (2016): 110-120. https://doi.org/10.1016/j.jaap.2016.04.015

[11] Alsultan, G. Abdulkareem, N. Asikin-Mijan, H. V. Lee, Ahmed S. Albazzaz, and Y. H. Taufiq-Yap. "Deoxygenation of waste cooking to renewable diesel over walnut shell-derived nanorode activated carbon supported CaO-La2O3 catalyst." Energy Conversion and Management 151 (2017): 311-323. https://doi.org/10.1016/j.enconman.2017.09.001

[12] He, Zhong, and Xianqin Wang. "Hydrodeoxygenation of model compounds and catalytic systems for pyrolysis biooils upgrading." Catalysis for sustainable energy 1 (2012): 28-52. https://doi.org/10.2478/cse-2012-0004

[13] Asphaug, Sindre. "Catalytic hydrodeoxygenation of bio-oils with supported MoP-catalysts." Master's thesis, Institutt for kjemisk prosessteknologi, 2013. https://doi.org/10.1016/S1351-4180(13)70472-0

[14] Aliana-Nasharuddin, N., N. Asikin-Mijan, G. Abdulkareem-Alsultan, Mohd Izham Saiman, Fahad A. Alharthi, Abdulaziz Ali Alghamdi, and Y. H. Taufiq-Yap. "Production of green diesel from catalytic deoxygenation of chicken fat oil over a series binary metal oxide-supported MWCNTs." RSC Advances 10, no. 2 (2020): 626-642. https://doi.org/10.1039/C9RA08409F

[15] Yao, S. G. (2018). Oxidation of Β-O-4 Lignin Model Compounds and Application to Lignin Linkage Degradation Facilitated by Mechanochemical Treatment and Two-step Oxidative Depolymerization.  https://doi.org/10.13023/ETD.2018.023

[16] Hensley, A. J., Hong, Y., Zhang, R., Zhang, H., Sun, J., Wang, Y., & McEwen, J. S. (2014). Enhanced Fe2O3 reducibility via surface modification with Pd: Characterizing the synergy within Pd/Fe catalysts for hydrodeoxygenation reactions. Acs Catalysis, 4(10), 3381-3392.  https://doi.org/10.1021/cs500565e

[17] Sitthisa, S., Sooknoi, T., Ma, Y., Balbuena, P. B., & Resasco, D. E. (2011). Kinetics and mechanism of hydrogenation of furfural on Cu/SiO2 catalysts. Journal of catalysis, 277(1), 1-13.  https://doi.org/10.1016/j.jcat.2010.10.005

[18] Nikul’shin, P. A., Sal’nikov, V. A., Pimerzin, A. A., Eremina, Y. V., Koklyukhin, A. S., Tsvetkov, V. S., & Pimerzin, A. A. (2016). Co-hydrotreating of straight-run diesel fraction and vegetable oil on Co (Ni)-PMo/Al 2 O 3 catalysts. Petroleum Chemistry, 56(1), 56-61. DOI: 10.1134/S0965544115080150

[19] Tran, N. T., Uemura, Y., Chowdhury, S., & Ramli, A. (2016). Vapor-phase hydrodeoxygenation of guaiacol on AlMCM-41 supported Ni and Co catalysts. Applied Catalysis A: General, 512, 93-100. https://doi.org/10.1016/j.apcata.2015.12.021

[20] Alharbi, K., Kozhevnikova, E. F., & Kozhevnikov, I. V. (2015). Hydrogenation of ketones over bifunctional Ptheteropoly acid catalyst in the gas phase. Applied Catalysis A: General, 504, 457-462.  https://doi.org/10.1016/j.apcata.2014.10.032

[21] Dawes, Gwen J. S., Elinor L. Scott, Jérôme Le Nôtre, Johan PM Sanders, and Johannes H. Bitter. "Deoxygenation of biobased molecules by decarboxylation and decarbonylation–a review on the role of heterogeneous, homogeneous and bio-catalysis." Green Chemistry 17, no. 6 (2015): 3231-3250. https://doi.org/10.1039/C5GC00023H

[22] Xiaoyan, Sun, Wang Rui, and S. U. Dangsheng. "Research progress in metal-free carbon-based catalysts." Chinese Journal of Catalysis 34, no. 3 (2013): 508-523.

[23] Ampelli, Claudio, Siglinda Perathoner, and Gabriele Centi. "Carbon-based catalysts: opening new scenario to develop next-generation nano-engineered catalytic materials." Chinese Journal of Catalysis 35, no. 6 (2014): 783-791. https://doi.org/10.1016/S1872-2067(14)60139-X

[24] Zhou, Weijia, Jin Jia, Jia Lu, Linjing Yang, Dongman Hou, Guoqiang Li, and Shaowei Chen. "Recent developments of carbon-based electrocatalysts for hydrogen evolution reaction." Nano Energy 28 (2016): 29-43. https://doi.org/10.1016/j.nanoen.2016.08.027

[25] Robinson, Allison M., Jesse E. Hensley, and J. Will Medlin. "Bifunctional catalysts for upgrading of biomass-derived oxygenates: a review." ACS catalysis 6, no. 8 (2016): 5026-5043. https://doi.org/10.1021/acscatal.6b00923

[26] Fau, Guillaume, Nicolas Gascoin, and Johan Steelant. "Hydrocarbon pyrolysis with a methane focus: a review on the catalytic effect and the coke production." Journal of Analytical and Applied Pyrolysis 108 (2014): 1-11. https://doi.org/10.1016/j.jaap.2014.05.022

[27] Dutta, Saikat. "Deoxygenation of biomass?derived feedstocks: hurdles and opportunities." ChemSusChem 5, no. 11 (2012): 2125-2127. https://doi.org/10.1002/cssc.201200596

[28] Popov, Sergiy, and Sandeep Kumar. "Renewable fuels via catalytic hydrodeoxygenation of lipid-based feedstocks." Biofuels 4, no. 2 (2013): 219-239. https://doi.org/10.4155/bfs.12.89

[29] Pattanaik, Bhabani Prasanna, and Rahul Dev Misra. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review." Renewable and Sustainable Energy Reviews 73 (2017): 545-557. https://doi.org/10.1016/j.rser.2017.01.018

[30] Griffin, Michael B., Glen A. Ferguson, Daniel A. Ruddy, Mary J. Biddy, Gregg T. Beckham, and Joshua A. Schaidle. "Role of the support and reaction conditions on the vapor-phase deoxygenation of m-cresol over Pt/C and Pt/TiO2 catalysts." ACS Catalysis 6, no. 4 (2016): 2715-2727. https://doi.org/10.1021/acscatal.5b02868

[31] Santillan-Jimenez, Eduardo, Tonya Morgan, Joseph Lacny, Susanta Mohapatra, and Mark Crocker. "Catalytic deoxygenation of triglycerides and fatty acids to hydrocarbons over carbon-supported nickel." Fuel 103 (2013): 1010-1017. https://doi.org/10.1016/j.fuel.2012.08.035

[32] Chen, Song. "Green oil production by hydroprocessing." International Journal ofClean Coal and Energy 1, no. 4 (2012): 43-55. https://doi.org/10.4236/ijcce.2012.14005

[33] Choudhary, Tushar V., and Cory B. Phillips. "Renewable fuels via catalytic hydrodeoxygenation." Applied Catalysis A: General 397, no. 1-2 (2011): 1-12. https://doi.org/10.1016/j.apcata.2011.02.025

[34] Jahirul, Mohammad I., Mohammad G. Rasul, Ashfaque Ahmed Chowdhury, and Nanjappa Ashwath. "Biofuels production through biomass pyrolysis—a technological review." Energies 5, no. 12 (2012): 4952-5001. https://doi.org/10.3390/en5124952


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