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Type :thesis
Subject :TP Chemical technology
Main Author :Nursuhaila Mohd Nor Rulhadi
Title :Characterisation of dental resin composite with natural and synthetic hydroxyapatite-yttria stabilised zirconia fillers
Place of Production :Tanjong Malim
Publisher :Fakulti Sains dan Matematik
Year of Publication :2019
Notes :with cd
Corporate Name :Universiti Pendidikan Sultan Idris
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Abstract : Universiti Pendidikan Sultan Idris
This  study aimed  to  prepare and  characterise  dental  resin  composite with hydroxyapatite-yttria stabilised zirconia (HAp-YSZ) fillers from natural and synthetic sources of  hydroxyapatite (HAp). The yttria stabilised zirconia (YSZ) and HAp were used as reinforcement  inorganic fillers, while the organic resin were the blended monomers of bisphenol A glycerolate  dimethacrylate (Bis-GMA), triethylene glycol dimethacrylate (TEGDMA) and diurethane dimethacrylate  (UDMA). The composites were thoroughly blended at ratio of 70:30 wt/wt of fillers and resin. The  mixing ratios of fillers (YSZ:HAp) were fixed at 0:100; 10:90; 25:75; 50:50 and 75:25 wt/wt. The  composites were moulded and crosslinked under UV-light for 60 s on the both sides of samples  surfaces. The degree of conversion, flexural strength (FS), compression strength (CS), Vickers  hardness (VH), surface roughness (SR), water sorption, water solubility and cytotoxicity of  composites were measured. The results exhibited that the mechanical properties of YSZ-natural HAp  composites with ratio of 10:90 wt/wt (FS = 65.61 MPa; CS = 160.34 MPa; VH = 50.80 HV; SR = 120.00  nm) were better performance than YSZ-synthetic HAp composites. Water sorption and solubility of this composite are  25.19 µg mm?³ and 5.58 µg mm?³, respectively. The cytotoxicity test showed that this compositeis  non-toxic. As a conclusion, HAp-YSZ dental resin composites were successfully prepared and  characterised. The implication of this study is that the composite produced shows a potential to be  used as dental resin composite.  

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