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Type :thesis
Subject :QC Physics
Main Author :Azyuni Aziz
Title :Pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer P3HT/partikel-partikel nano CdS dan CdSe
Place of Production :Tanjong Malim
Publisher :Fakulti Sains dan Matematik
Year of Publication :2021
Corporate Name :Universiti Pendidikan Sultan Idris
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Abstract : Universiti Pendidikan Sultan Idris
Kajian ini bertujuan untuk melakukan pencirian morfologi, optik dan struktur bagi mengkaji kehadiran partikel-partikel nano CdS dan CdSe yang tertanam di antara matriks P3HT peranti filem nipis hibrid organik dan tak organik menggunakan teknik Pemendapan Angkutan Sudut (ALD) dan kaedah dedahan gas yang mudah, cepat dan berkos rendah. Penyelidikan bermula dengan menentukan kesan kehadiran ion Cd2+ dalam larutan P3HT, asid stearik (SA) dan P3HT:SA yang dicirikan dengan isoterma tekanan permukaan-luas yang dikawal oleh komputer. Peranti filem nipis disediakan dengan memendapkan P3HT, SA dan ion Cd2+ (dalam kemolaran 0.5 dan 1.0 mM CdCl2) ke atas substrat silikon dan kuarza menggunakan teknik ALD dan dedahan kepada gas H2S atau H2Se selama 2, 4, 6 dan 15 jam. Peranti filem nipis organik-tak organik dicirikan menggunakan FESEM, EDX, AFM, spektroskopi Raman dan UVVis. Pencirian isoterma tekanan permukaan-luas menunjukkan purata keluasan dan saiz molekul P3HT, SA dan P3HT:SA meningkat dengan peningkatan ion Cd2+. Pembentukan partikel-partikel nano berjaya ditanam di antara matriks P3HT dengan menggunakan kedua-dua kaedah seperti yang disahkan oleh keputusan FESEM, EDX dan AFM. Pencirian Raman menunjukkan anjakan puncak ke nombor gelombang lebih rendah apabila tempoh dedahan meningkat, menunjukkan peningkatan dalam kristalografi polimer P3HT dan perlanjutan panjang konjugasi yang berkesan di sepanjang tulang belakang polimer. Pencirian optik UV-Vis menunjukkan nilai tenaga lebar jalur adalah antara 1.87 sehingga 1.91 eV. Sebagai kesimpulan, hasil pencirian morfologi, optik dan struktur menunjukkan kehadiran partikel-partikel nano CdS atau CdSe yang tertanam di antara matriks P3HT menggunakan kaedah ALD dan dedahan gas. Polimer hibrid terbaik ialah P3HT:CdS dalam kemolaran 0.5 mM CdCl2 yang didedahkan selama 6 jam. Kajian ini memberi implikasi bahawa teknik pemendapan ALD dan dedahan gas adalah praktikal untuk menghasilkan peranti hibrid nanokomposit organik-tak organik berkos rendah.

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