Correlation of langmuir isotherm, optical, surface potential and morphological characterizations of two functionalized dihydroxycalix [4] arene for lead cation entrapment

Faridah Lisa Supian

QR Code Link :
Type :	article
Subject :	QA Mathematics
ISSN :	1823-7010
Main Author :	Faridah Lisa Supian
Additional Authors :	Noor Azyyati Azahari Yusnita Juahir Nur Farah Nadia Abd Karim
Title :	Correlation of langmuir isotherm, optical, surface potential and morphological characterizations of two functionalized dihydroxycalix [4] arene for lead cation entrapment

Place of Production :	Tanjung Malim
Publisher :	Fakulti Sains dan Matematik
Year of Publication :	2021
Notes :	Malaysian Journal of Microscopy
Corporate Name :	Universiti Pendidikan Sultan Idris
Web Link :	Click to view web link
PDF Full Text :	Login required to access this item.

Abstract : Universiti Pendidikan Sultan Idris

The versatilities of calixarenes have been known primarily in the host-guest world. In this work, two calix[4]arenes, namely C-DHC4 and N-DHC4, possess the same lower rim but are distinct in the upper rim. The Langmuir Isotherm and optical properties have been carried out using Langmuir?Blodgett trough and UV-Visible spectroscopy, respectively. The topographical image of the calix[4]arenes has been observed using FESEM, and lead cation entrapments of these calix[4]arenes have been inspected using the surface potential sensor. The isotherm graph revealed the size of each calixarene; C-DHC4 ~ 1.90 nm2 and N-DHC4 ~ 2.10 nm2 . The UV-Visible result demonstrated that each calix[4]arene has two firm absorption peaks where C-DHC4 has two broad peaks, which lie in 261 and 330 nm, while N-DHC4 has two shoulders at 275 and 282 nm. FESEM images have shown the formation of calix[4]arene nanocluster. Further monitoring on the surface potential and effective dipole moment indicate that C-DHC4 perform significant and stable results in detecting Pb2+ cations compared to N-DHC4. This study has demonstrated that detection limit as low as 1.25 x 10-2 mM, making the ?V and �? measurements a reliable method for detecting Pb2+ ions and their potential in this nanosensor field. ?Malaysian Journal of Microscopy (2021). All rights reserved.

References

Asfari, Z., Böhmer, V., Harrowfield, J., & Vicens, J. (2001). Calixarenes 2001, Retrieved from www.scopus.com

Azahari, N. A., Supian, F. L., Richardson, T. H., & Malik, S. A. (2014). Properties of calix4-lead(pb) films using langmuir-blodgett(LB) technique as an application of ion sensor doi:10.4028/www.scientific.net/AMR.895.8 Retrieved from www.scopus.com

Chachaj-Brekiesz, A., Kobierski, J., Wnȩtrzak, A., & Dynarowicz-Latka, P. (2021). Electrical properties of membrane phospholipids in langmuir monolayers. Membranes, 11(1), 1-11. doi:10.3390/membranes11010053

DarvinaLim, C. K., & Supian, F. L. (2017). Elucidation of properties in langmuir monolayers and langmuir-blodgett (LB) films formed by calix[6]arene. J.Fizik Malaysia, 38(1), 010034-010043. Retrieved from www.scopus.com

De Silva, A. P., Gunaratne, H. Q. N., Gunnlaugsson, T., Huxley, A. J. M., McCoy, C. P., Rademacher, J. T., & Rice, T. E. (1997). Signaling recognition events with fluorescent sensors and switches. Chemical Reviews, 97(5), 1515-1566. doi:10.1021/cr960386p

Doménech-Carbó, M. T., Álvarez-Romero, C., Doménech-Carbó, A., Osete-Cortina, L., & Martínez-Bazán, M. L. (2019). Microchemical surface analysis of historic copper-based coins by the combined use of FIB-FESEM-EDX, OM, FTIR spectroscopy and solid-state electrochemical techniques. Microchemical Journal, 148, 573-581. doi:10.1016/j.microc.2019.05.039

Jurak, M., Szafran, K., Cea, P., & Martín, S. (2021). Analysis of molecular interactions between components in phospholipid-immunosuppressant-antioxidant mixed langmuir films. Langmuir, 37(18), 5601-5616. doi:10.1021/acs.langmuir.1c00434

Liekkinen, J., de Santos Moreno, B., Paananen, R. O., Vattulainen, I., Monticelli, L., Bernardino de la Serna, J., & Javanainen, M. (2020). Understanding the functional properties of lipid heterogeneity in pulmonary surfactant monolayers at the atomistic level. Frontiers in Cell and Developmental Biology, 8 doi:10.3389/fcell.2020.581016

Lim, D. C. K., Supian, F. L., & Hamzah, Y. (2020). Langmuir, raman, and electrical properties comparison of calixarene and calixarene-rGO using langmuir blodgett (LB) technique. Journal of Materials Science: Materials in Electronics, 31(21), 18487-18494. doi:10.1007/s10854-020-04392-6

Lo Nostro, P., Capuzzi, G., Fratini, E., Dei, L., & Baglioni, P. (2001). Modulation of interfacial properties of functionalized calixarenes Retrieved from www.scopus.com

Lo Nostro, P., Casnati, A., Bossoletti, L., Dei, L., & Baglioni, P. (1996). Complexation properties of calixarenes in langmuir films at the water-air interface. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 116(1-2), 203-209. doi:10.1016/0927-7757(96)03584-4

Mohd Azmi, M. S., Noorizhab, M. F. F., Supian, F. L., & Malik, S. A. (2020). A review of calixarene Langmuir–Blodgett thin film characteristics for nanosensor applications. Defence S and T Technical Bulletin, 13(2), 205-216. Retrieved from www.scopus.com

Patra, S., Maity, D., Gunupuru, R., Agnihotri, P., & Paul, P. (2012). Calixarenes: Versatile molecules as molecular sensors for ion recognition study. Journal of Chemical Sciences, 124(6), 1287-1299. doi:10.1007/s12039-012-0329-y

Razali, A. S., Supian, F. L., Salleh, M. M., & Bakar, S. A. (2015). Characterization and detection of cadmium ion using modification calixarene with multiwalled carbon nanotubes. International Journal of Chemical and Molecular Engineering, 9(2), 304-307. Retrieved from www.scopus.com

Shinkai, S., Mori, S., Koreishi, H., Tsubaki, T., & Manabe, O. (1986). Hexasulfonated calix[6]arene derivatives: A new class of catalysts, surfactants, and host molecules. Journal of the American Chemical Society, 108(9), 2409-2416. doi:10.1021/ja00269a045

Supian, F. L., Richardson, T. H., Deasy, M., Kelleher, F., Ward, J. P., & Mckee, V. (2010). A surface potential study of ion-uptake by 5,11,17,23-tetra-tert-butyl-25, 27-diethoxycarbonyl methyleneoxy-26,28,dihydroxycalix[4]arene and 5,17-(3-nitrobenzylideneamino)-11, 23-di-tert-butyl-25,27-diethoxycarbonyl methyleneoxy-26,28-dihydroxycalix[4]arene langmuir blodgett (LB) monolayers. Sains Malaysiana, 39(3), 423-433. Retrieved from www.scopus.com

Supian, F. L., Richardson, T. H., Deasy, M., Kelleher, F., Ward, J. P., & McKee, V. (2010). Interaction between langmuir and langmuir-blodgett films of two calix[4]arenes with aqueous copper and lithium ions. Langmuir, 26(13), 10906-10912. doi:10.1021/la100808r

Yuan, Y., Zhang, B., Sun, J., Jonnard, P., Le Guen, K., Tu, Y., . . . Lan, R. (2020). Structure and optical properties of CrOxNy films with composition modulation. Surface Engineering, 36(4), 411-417. doi:10.1080/02670844.2019.1656356

This material may be protected under Copyright Act which governs the making of photocopies or reproductions of copyrighted materials.
You may use the digitized material for private study, scholarship, or research.

Back to previous page