UPSI Digital Repository (UDRep)
Start | FAQ | About
Menu Icon

QR Code Link :

Type :article
Subject :Q Science (General)
ISSN :1411-9420
Main Author :Noorshida Mohd Ali
Additional Authors :Yusnita Juahir
Norhayati Hashim
Illyas Md Isa
Azmi Mohamed
Azlan Kamari
Title :Synthesis, spectroscopic, and photophysical studies of phosphorescent Bis(2-(2,4-difluorophenyl)pyridine)Iridium(III) complex containing derivative of 1H-1,2,4-triazole anchillary ligand
Place of Production :Tanjung Malim
Publisher :Fakulti Sains dan Matematik
Year of Publication :2021
Notes :Indonesian Journal of Chemistry
Corporate Name :Universiti Pendidikan Sultan Idris
HTTP Link :Click to view web link

Abstract : Universiti Pendidikan Sultan Idris
A cationic complex of iridium(III), [Ir(2,4-F2ppy)2 (F2 bpyta)]PF6 utilizing 1,2,4-triazolepyridyl as an anchillary ligand modified with a 2,6-difluorobenzyl substituent was synthesized and characterized. The aromatic signals of pyridyltriazole and phenylpyridine proton were detected in the1 H-NMR spectrum between 10.00 and 7.00 ppm. Only one singlet peak was detected at 8.46 ppm H(8) shifted to the upfield, demonstrating that C5 was coordinated to the central iridium metal. The bands exhibited in the range of 1555?1431 cm?1 in the IR spectrum because of the C=C and C=N aromatic rings stretching pyridine, phenyl, and triazole vibrations. The UV-Vis absorption spectrum showed a slight and broad absorbance peak at lower energy at a lmax = 371 nm (e = 6129 M?1 cm?1) in the visible range due to1 MLCT and3 MLCT transitions. Blue emission was observed in the steady-state emission spectral of [Ir(2,4-F2 ppy)2 (F2 bpyta)]PF6 and the other two previously synthesized iridium(III) complexes in CH2 Cl2 solutions (air-equilibrated) at room temperature. The spectrum of luminescence for the [Ir(2,4-F2 ppy)2 (F2 bpyta)]PF6 (lem = 461 nm) is blue-shifted when compared to the [Ir(2,4-F2 ppy)2 (hpyta)]PF6 (lem = 469 nm), but red-shifted when related to the [Ir(2,4-F2 ppy)2 (mbpyta)]PF6 (lem = 454 nm). ? 2021, Gadjah Mada University. All rights reserved.

References

Ali, N.M., Ward, M.D., Hashim, N., and Daud, N., 2017, Synthesis and photophysical properties of bis(phenylpyridine) iridium(III) dicyanide complexes, Mater. Res. Innovations, 23 (3), 135–140.

Barbante, G.J., Doeven, E.H., Francis, P.S., Stringer, B.D., Hogan, C.F., Kheradmand, P.R., Wilson, D.J.D., and Barnard, P.J., 2015, Iridium(III) N-heterocyclic carbene complexes: An experimental and theoretical study of structural, spectroscopic, electrochemical and electrogenerated chemiluminescence properties, Dalton Trans., 44 (18), 8564–8576. 

Lee, S., and Han, W.S., 2020, Cyclometalated Ir(III) complexes towards blue-emissive dopant for organic  light-emitting diodes: fundamentals of photophysics and designing strategies, Inorg. Chem. Front., 7 (12), 2396–2422.

Si, Y., Zang, S., Gahungu, G., Yang, J., and Wu, Z., 2015, Modification of the emission colour and quantum efficiency for oxazoline- and thiazolinecontaining Iridium complexes via different N^O, RSC Adv., 5 (24), 18464–18470.

Costa, R.D., Ortí, E., Bolink, H.J., Monti, F., Accorsi, G., and Armaroli, N., 2012, Luminescent ionic transition-metal complexes for light-emitting electrochemical cells, Angew. Chem. Int. Ed., 51 (33), 8178–8211.

Adeloye, A.O., Mphahlele, M.J., Adekunle, A.S., Rhyman, L., and Ramasami, P., 2017, Spectroscopic, electrochemical and DFT studies of phosphorescent homoleptic cyclometalated iridium(III) complexes based on substituted 4-fluorophenylvinyland 4- methoxyphenylvinylquinolines, Materials, 10 (10), 1061.

Aghazada, S., Huckaba, A.J., Ojeda, A.P., Babaei, A., Grancini, G., Zimmermann, I., Bolink, H., and Nazeeruddin, M.K., 2016, Molecular engineering of iridium blue emitters using aryl N-heterocyclic carbene ligands, Eur. J. Inorg. Chem., 2016 (32), 5089–5097.

Li, H., Yin, Y.M., Cao, H.T., Sun, H.Z., Wang, L., Shan, G.G., Zhu, D.X., Su, Z.M., and Xie, W.F., 2014, Efficient greenish-blue phosphorescent iridium(III) complexes containing carbene and triazole chromophores for organic light-emitting diodes, J. Organomet. Chem., 753, 55–62.

Flifel, I.A., and Hlail, A.N., 2017, Preparation, spectra characterization of new 1,2,4-triazole derivatives and its complexities with some transition metal ions, Int. J. Appl. Eng. Res., 12 (24), 14878–14881.

Pal, A.K., Cordes, D.B., Pringouri, K., Anwar, M.U., Slawin, A.M.Z., Rawson, J.M., and ZysmanColman, E., 2016, Synthesis and characterization of green-to-yellow emissive Ir(III) complexes of pyridylbenzothiadiazine ligand, J. Coord. Chem., 69 (11-13), 1924–1937. 

Rentzsch, C.F., Tosh, E., Herrmann, W.A., and Kühn, F.E., 2009, Iridium complexes of Nheterocyclic carbenes in C–H borylation using energy efficient microwave technology: Influence of structure, ligand donor strength and counter ion on catalytic activity, Green Chem., 11 (10), 1610–1617.

Omae, I., 2016, Application of the five-membered ring blue light-emitting iridium products of cyclometalation reactions as OLEDs, Coord. Chem. Rev., 310, 154–169.

Ahn, S.Y., Lee, H.S., and Ha, Y., 2011, New blue phosphorescent iridium complexes containing phenylpyridine and triazole ligands: Synthesis and luminescence studies, J. Nanosci. Nanotechnol., 11 (5), 4414–4418.

Bain, N.H.A.S., Ali, N.M., Juahir, Y., Hashim, N., Isa, I.M., Mohamed, A., Kamari, A., Anouar, E.H., Yamin, B.M., Tajuddin, A.M., and Baharudin, M.H., 2020, Synthesis, crystal structure, photophysical properties, DFT studies and Hirshfeld surface analysis of a phosphorescent 1,2,4-triazole-based iridium(III) complex, Polyhedron, 188, 114690.

Bain, N.H.A.S., Ali, N.M., Juahir, Y., Hashim, N., Isa, I.M., Mohamed, A., Kamari, A., and Yamin, B.M., 2018, Synthesis of phenylpyridine iridium(III) complexes with N-heterocyclic carbene as ancillary ligands, IOP Conf. Ser.: Mater. Sci. Eng., 440, 012010.

Henwood, A.F., Bansal, A.K., Cordes, D.B., Slawin, A.M.Z., Samuel, I.D.W., and Zysman-Colman, E., 2016, Solubilised bright blue-emitting iridium complexes for solution processed OLEDs, J. Mater. Chem. C, 4 (17), 3726–3737.  

Barbante, G.J., Francis, P.S., Hogan, C.F., Kheradmand, P.R., Wilson, D.J.D., and Barnard, P.J., 2013, Electrochemiluminescent ruthenium(II) Nheterocyclic carbene complexes: A combined experimental and theoretical study, Inorg. Chem., 52 (13), 7448–7459.

He, L., Wang, Z., Duan, L., Yang, C., Tang, R., Song, X., and Pan, C., 2016, Toward fluorine-free blueemitting cationic iridium complexes: To generate emission from the cyclometalating ligands with enhanced triplet energy, Dalton Trans., 45 (13), 5604–5613.

Gökce, H., Öztürk, N., Taşan, M., Alpaslan, Y.B., and Alpaslan, G., 2016, Spectroscopic characterization and quantum chemical computations of the 5-(4- pyridyl)-1H-1,2,4-triazole-3-thiol molecule, Spectrosc. Lett., 49 (3), 167–179.

Beldovskaya, A.D., Dushenko, G.A., and Vikrishchuk, N.I., 2013, Synthesis, structure, and spectral luminescent properties of novel 1,2,4- triazole derivatives containing benzthiazole group, Russ. J. Gen. Chem., 83 (11), 2075–2083.

Sanner, R.D., Cherepy, N.J., and Young, V.G., 2016, Blue light emission from cyclometallated iridium(III) cyano complexes: Syntheses, crystal structures, and photophysical properties, Inorg. Chim. Acta, 440, 165–171.

Stringer, B.D., Quan, L.M., Barnard, P.J., Wilson, D.J.D., and Hogan, C.F., 2014, Iridium complexes of N-heterocyclic carbene ligands: Investigation into the energetic requirements for efficient electrogenerated chemiluminescence, Organometallics, 33 (18), 4860–4872.

Monti, F., Kessler, F., Delgado, M., Frey, J., Bazzanini, F., Accorsi, G., Armaroli, N., Bolink, H.J., Orti, E., Scopelliti, R., Nazeeruddin, M.K., and Baranoff, E., 2013, Charged bis-cyclometalated iridium(III) complexes with carbene-based ancillary ligands, Inorg. Chem., 52 (18), 10292–10305.

Baranoff, E., Curchod, B.F.E., Monti, F., Steimer, F., Accorsi, G., Tavernelli, I., Rothlisberger, U., Scopelliti, R., Grätzel, M., and Nazeeruddin, M.K., 2012, Influence of halogen atoms on a homologous series of bis-cyclometalated iridium(III) complexes, Inorg. Chem., 51 (2), 799–811.

Pla, P., Junquera-Hernández, J.M., Bolink, H.J., and Ortí, E., 2015, Emission energy of azole-based ionic iridium(III) complexes: A theoretical study, Dalton Trans., 44 (18), 8497–8505.

Tamayo, A.B., Alleyne, B.D., Djurovich, P.I., Lamansky, S., Tsyba, I., Ho, N.N., Bau, R., and Thompson, M.E., 2013, Synthesis and characterization of facial and meridional triscyclometalated iridium(III) complexes, J. Am. Chem. Soc., 125 (24), 7377–7387.

Wang, Z., He, L., Duan, L., Yan, J., Tang, R., Pan, C., and Song, X., 2015, Blue-green emitting cationic iridium complexes with 1,3,4-oxadiazole cyclometallating ligands: Synthesis, photophysical and electrochemical properties, theoretical investigation and electroluminescent devices, Dalton Trans., 44 (36), 15914–15923.


This material may be protected under Copyright Act which governs the making of photocopies or reproductions of copyrighted materials.
You may use the digitized material for private study, scholarship, or research.

Back to previous page

Installed and configured by Bahagian Automasi, Perpustakaan Tuanku Bainun, Universiti Pendidikan Sultan Idris
If you have enquiries, kindly contact us at pustakasys@upsi.edu.my or 016-3630263. Office hours only.