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Total records found : 1
Simplified search suggestions : Suriani binti Abu Bakar
12021
Article
Low nickel, ceria zirconia-based micro-tubular solid oxide fuel cell: A study of composition and oxidation using hydrogen and methane fuel
Suriani binti Abu Bakar
The study examines the effect of using low nickel (Ni) with high ceria (CeO2) anode content towards the oxidation of H2 and CH4 fuel by evaluating the activation energy of the ohmic process and charge transfer process. Using a micro-tubular solid oxide fuel cell (MT-SOFC), the anodes are made up of 50% YSZ with varying NiO:CeO2 percentages from 0% NiO, 50% CeO2 to 50% NiO, 0% CeO2. The performance is measured based on maximum power density (MPD), electrochemical impedance spectroscopy (EIS) and activation energy, Ea of the ohmic (Rohm) and charge transfer (Rct) processes. We found that by lowering the Ni content to lower than 50% NiO, anode conductivity will drop by 7-fold. An anode containing 37.5% NiO, 12.5% CeO2 yield MPD of 41.1 and 2.9 mW cm−2 when tested on H2 and CH4 fuels thus have the lowest Ni content without an abrupt negative effect on the MPD and EIS. The significant effect of conductivity drops on MPD and EIS are observed to occur at 25% NiO, 25% CeO2 and lowe.....

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