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UPSI Digital Repository (UDRep)
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| Total records found : 2 |
| Simplified search suggestions : Umar Saad Aliyu |
| 1 | 2018 Article | The structural, physical and optical properties of borotellurite glasses incorporated with silica from rice husk Umar Saad Aliyu From the agricultural waste of rice (rice husk), high purity SiO2 with about 98.548 % purity was extracted using a very simple room temperature leaching method. Using the rice husk extracted silicate, a system of silicate borotellurite glasses was fabricated with composition equation [(TeO2)0.7 (B2O3)0.3]1-x (SiO2)x with x= 0.0, 0.1, 0.2, 0.3 and 0.4. The density and molar volume were measured, and Fourier transform infrared (FTIR), X-ray diffraction (XRD) and UV-Vis analyses were performed on the glasses. Both the density and molar volume decreased and the XRD pattern confirmed the glasses’ amorphous nature. The FTIR showed the presence of TeO3, TeO4, BO3, BO2O, SiO4, and H3BO3 structural units in the glasses. The concentrations of TeO3, TeO4, BO3 and BO2O structures were determined by the deconvolution of the FTIR spectra using an Origin software. The optical energy band gap, index of refraction, oxygen packing density (OPD), molar refractive index, metallization criterion and pola..... 959 hits |
| 2 | 2021 Article | Oxide ion/electronic polarizability, optical basicity and linear dielectric susceptibility of TeO2 - B2O3 - SiO2 glasses Saad Aliyu Umar A system of bio-silica borotellurite glasses was fabricated based on the chemical formula [(TeO2)0.7 (B2O3)0.3]1-x (SiO2)x with x = 0.1, 0.2, 0.3, and 0.4 using the melt-quenching technique using silica (98.548% SiO2, from rice husk), TeO2 (Alfar Aeser, 99.9%) and B2O3 (Alfar Aeser, 99.9%). Measurements and characterizations such as density and molar volume measurements, XRD analysis, FTIR, and UV?Vis spectroscopes were performed on the studied glasses. The objective was to determine the glasses? applicability in optoelectronics, non-linear optics, and laser technologies through polarizability, linear electric susceptibility, and optical basicity study. Apart from confirming the amorphous nature of the glasses, the XRD analysis identified the presence of a crystalline phase of tellurium oxide (?-TeO2) formed. The FTIR spectral study revealed the presence of TeO3, BO3, and SiO4 structural units in the studied glasses. The refractive index (2.3026 ? 2.2651), molar polarizability (8.0696 ..... 919 hits |